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CBSE

Subject

Chemistry
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NEET Chemistry : Organic Chemistry – Some Basic Principles and Techniques

Multiple Choice Questions

181.

Which of the following carbocations will be most stable ?

  • Ph3C+

  • CH3-C+H2

  • (CH3)2C+H

  • CH2=CH-C+H2



182.

Among the following structures the one which is not a resonating structure of others is

  • I

  • II

  • III

  • IV



183.

A compound is formed by substitution of two chlorine for two hydrogens in propane. The number of possible isomeric compounds is

  • 4

  • 3

  • 2

  • 5



184.

Which one of the following will show optical isomerism?

  • OH-CH2-CO2H

  • CH3-CH(OH)-CO2H

  • (CH3)2-CH-CO2H

  • (CH3)2-C(Cl)-CO2H



185.

Among the following statements about the molecules X and Y, the one(s) which correct is (are)

  • X and Y are diastereomers

  • X and Y are enantiomers

  • X and Y are both aldohexoses

  • X is a D-sugar and Y is an L-sugar



186.

The well-known compounds, (+)- lactic acid and (-)- lactic acid, have the same molecular formula, C3H6O3. The correct relationship between them is:

  • constitutional isomerism

  • geometrical isomerism

  • identicalness

  • optical isomerism



187.

The two structures written below represent

             

  • pair of diastereomers

  • pair of enantiomers

  • same molecule

  • both are optically inactive



Short Answer Type

188.

Explain why aniline is not as basic as ammonia.



Multiple Choice Questions

189.

Which one of the following characteristics belong to an electrophile?

  • It is any species having electron deficiency which reacts at an electron-rich C-centre

  • It is any species having electron enrichment, that reacts at an electron-deficient C-centre

  • It is cationic in nature

  • It is anionic in nature



190.

Among the following carbocations:

Ph2C+CH2Me (I), PhCH2CH2CH+Ph (II), Ph2CHCH+Me (III) and Ph2C(Me)CH2 (IV), the order of stability is:

  • IV > II > I > III

  • I > II > III > IV

  • II > I > IV > III

  • I > IV > III > II



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