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CBSE

Subject

Chemistry
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NEET Chemistry : Organic Chemistry – Some Basic Principles and Techniques

Multiple Choice Questions

71.

The number of enantiomers and mesa forms for the compound , 

HOOC-CH(CH3)-CHOH-CHBr-CHOHCH(CH3)-COOH are respectively:

  • 12 , 2

  • 12 , 4

  • 8 , 4

  • 8 , 2



72.

Most acidic is

  • CH3COOH

  • C6H5CH2COOH

  • HCOOH

  • CH3CH2COOH



73.

The correct IUPAC name of

is:

  • 4-methyoxy -2- nitrobenzaldehyde

  • 4-formyl -3- nitro anisole

  • 4- methoxy -6- nitrobenzaldehyde

  • 2-formyl -5- methoxy nitrobenzene



74.

Which carbocation is most stable ?

  • CH3CH2+

  • CH3+

  • C6H5CH2+

  • CH3CH2CH2+



75.

The IUPAC name of the following compound is

  • bicyclo [2, 2, 0] octane

  • bicyclo [0, 2, 2] hexane

  • bicyclo [2, 1, 1] hexane

  • bicyclo [2, 2, 0] hexane



76.

The correct order of stability of carbocations, is :

  • 1° < 2° < 3° < CH3

  • C+H3 < 1° < 2° < 3°

  • 3° < 2° < 1° < C+H3

  • 2° < 3° < 1° < C+H3



77.

Which of the following is the correct increasing order of stability of free radicals.

  • (CH3)2CH0 < (CH3)2CH0 < (C6H5)20CH < (C6H5)3C0

  • (CH3)2CH0 < (CH3)2C0 < (C6H5)30C < (C6H5)2C0

  • (C6H5)30C < (C6H5)20CH < (CH3)30C < (CH3)20CH

  • (C6H5)20CH < (C6H5)2C0 < (CH3)30C < (CH3)20CH



78.

The following compound can not exhibit

CH3CH = CH - CH(OH).COOH

  • geometrical isomerism

  • optical isomerism

  • metamerism

  • position isomerism



79.

CH3C(CH2CH3) = CH(CH3H2catalyst X. No. of optical isomer possible will be

  • 2

  • 4

  • 0

  • 3



80.

Which of the following yields as a major product is mono chlorination of ethyl benzene in the presence of light and heat.

  • m- chlorotoluene

  • a mixture of -O- and p-chlorotoluene

  • 1-chloro-2- phenylethane

  • 1-chloro -1- phenyl ethane



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