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CBSE

Subject

Chemistry
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NEET Chemistry : Organic Chemistry – Some Basic Principles and Techniques

Multiple Choice Questions

121.

Which of the following conditions is not correct for resonating structures?

  • The contributing structures must have the same number of unpaired electrons.

  • The contributing structures should have similar energies.

  • The contributing structures should be so written that unlike charges reside on atoms that are far apart.

  • The positive charge should be present on the electropositive element and the negative charge on the electronegative element.



122.

The strained tetracyclic alkane is isomerize thermally to the cyclic alkene. The reaction involves

  • free radical

  • carbocation

  • carbanion

  • carbene.



123.

Decreasing order of nucleophilicity is

  • OH- > NH2- > CH3O- > RNH2

  • NH2- > OH- > CH3O- > RNH2

  • NH2- > CH3O- > OH- > RNH2

  • CH3O- > NH2- > OH- > RNH2



124.

Find the number of stereoisomers of 1,2-dihydroxy cyclopentane.

  • 1

  • 2

  • 3

  • 4



125.

Which is optically inactive?



126.

Assertion : C(CH3)3-CH2-Br + NaOH C(CH3)2OH-CH2-CH3

Reason : It follows with formation of more stable carbocation.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.



127.

Best method to form aromatic iodide is

  • ArN2+ + KI 

  • RNH2 + I2 

  • ArN2+ + KI 

  • ArN2+ + PI3 



128.

How much amount of CuSO4.5H2O is required for liberation of 2.54 g of I2 when titrated with KI?

  • 2.5 gm

  • 4.99 gm

  • 2.4 gm

  • 1.2 gm



129.

How many chiral carbonatoms are present in 2 , 3 , 4 - trichloropentane ?

  • 4

  • 1

  • 2

  • 3



130.

+ I effect is shown by :

  • -CH3

  • -Br

  • -Cl

  • -NO2



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