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CBSE

Subject

Chemistry
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NEET Chemistry : Solutions

Multiple Choice Questions

91.

A mixture of two miscible liquids A and B is distilled under equilibrium conditions at 1 atm pressure. The mole fraction of A in solution and vapour phase are 0.30 and 0.60 respectively. Assuming ideal behaviour of the solution and the vapour, calculate the ratio of the vapour pressure of pure A to that of pure B.

  • 4.0

  • 3.5

  • 2.5

  • 1.85



92.

If two substances A and B have PA° : PB° = 1 : 2 and have mole fraction in solution 1 : 2 then mole fraction of A in vapours :

  • 0.33

  • 0.25

  • 0.52

  • 0.2



93.

To a 25 mL H2O2 solution, excess of acidified solution of Kl was added. The iodine liberated required 20 ml of 0.3 N Na2S2O3 solution. The volume strength of H2O2 solution is

  • 1.344 g/L

  • 3.244 g/L

  • 5.4 g/L

  • 4.08 g/L



94.

Assertion : A non volatile solute is mixed in a solution then elevation in boiling point and depression in freezing point both are 2 K.

Reason : Elevation in boiling point and depression in freezing point both depend on melting point of non-volatile solute.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.



95.

1 mol each of the following compounds is dissolved in 1L of solution. Which will have the largest Tb value?

  • HF

  • HCl

  • HBr

  • HI



96.

The mass of glucose that should be dissolved in SO g of water in order to produce the same lowering of vapour pressure as is produced by dissolving 1 g of urea in the same quantity of water is :

  • 1 g

  • 3 g

  • 6 g

  • 18 g



97.

For a dilute solution, Raoult's law states that

  • the relative lowering of vapour pressure is proportional to the amount of solute in solution

  • the relative lowering of vapour pressure is equal to the mole fraction of solute

  • the lowering of vapour pressure is equal to the mole fraction of the solute

  • the vapour pressure of the solution is equal to the mole fraction of the solvent.



98.

A 0.1 molal solution of an acid is 4.5% ionized. Calculate freezing point. (molecular weight of the acid is 300). K= 1.86 K mol-1 kg.

  • -0.194°C

  • 2.00°C

  • 0°C

  • -0.269°C



99.

Which is not a colligative property ?

  • Refractive index

  • Lowering of vapour pressure

  • Depression in freezing point

  • Elevation in boiling point



100.

Osmotic pressure observed when benzoic acid is dissolved in benzene is less than that expected from theoretical considerations .This is because :

  • benzoic acid is an organic solute

  • benzoic acid has higher molar mass than benzene

  • benzoic acid gets associated in benzene

  • benzoic acid gets dissociated in benzene



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