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CBSE

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Chemistry
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NEET Chemistry : The d-And-f-Block Elements

Multiple Choice Questions

1.

KMnO4 can be prepared from K2MnO4 as per reaction
3 MnO subscript 4 superscript 2 minus end superscript space plus 2 straight H subscript 2 straight O space rightwards harpoon over leftwards harpoon 2 MnO subscript 4 superscript minus space plus MnO subscript 2 space plus 4 OH to the power of minus
The reaction can go to completion by removing OH- ions by adding

  • HCl

  • KOH

  • CO2

  • CO2



2.

Because of lanthanoid contraction, of elements which of the following elements have nearly same atomic radii ? (Number in the parenthesis are atomic number).

  • Ti (22) and Zr(40)

  • Zr(40) and Nb (41)

  • Zr (40) and Hf (72)

  • Zr (40) and Hf (72)



3.

Which of the following does not give oxygen on heating?

  • KClO3

  • Zn(ClO3)2

  • K2Cr2O7

  • K2Cr2O7



4.

When copper is heated with conc. HNO3 it produces

  • Cu(NO3)2 and NO

  • Cu(NO3)2, NO and NO2

  • Cu(NO3)2 and N2O

  • Cu(NO3)2 and N2O



5.

Which of the following lanthanoid ions is diamagnetic?
(At. number; Ce =58, Sm =62, Eu =63, Yb = 70)

  • Ce2+

  • Sm2+

  • Eu2+

  • Eu2+



6.

Which one of the following statements is correct when SO2 is passed through acidified K2Cr2O7 solution?

  • The solution is decolourized

  • SO2 is reduced

  • Green Cr2(SO4)3 is formed

  • The solution turns blue



7.

Four successive members of the first series of the transition metals are listed below. For which one of them, the standard potential valueleft parenthesis straight E subscript straight M to the power of 2 plus end exponent divided by straight M end subscript superscript straight o right parenthesis has a positive sign?

  • Co (Z=27)

  • Ni (Z=28)

  • Cu (Z=29)

  • Cu (Z=29)



8.

In acidic medium,H2O2 changes Cr2O72- to CrO5 which has two (-O-O-) bonds. Oxidation state of Cr in CrO3 is 

  • +5

  • +3

  • +6

  • +6



9.

Which one of the following does not correctly represent the correct order of the property indicated aginst it? 

  • Ti < V<Cr< Mn: increasing number of oxidation states

  • Ti< V<Cr3+<Mn3+ : increasing magnetic moment

  • Ti < V < Cr < Mn : Increasing melting points

  • Ti < V < Cr < Mn : Increasing melting points



10.

Reason of lanthanoid contraction is

  • negligible Screening effect of 'f' orbitals

  • increasing the nuclear charge

  • decreasing the nuclear charge

  • decreasing the nuclear charge



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