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CBSE

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Chemistry
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NEET Chemistry : The d-And-f-Block Elements

Multiple Choice Questions

121.

Cupric compounds are more stable than their cuprous counterparts in solid state. This is because

  • the endothermic character of the 2nd IP of Cu is not so high

  • size of Cu2+ is less than Cu+

  • Cu2+ has stable electronic configuration as compared to Cu+

  • the lattice energy released for cupric compounds is much higher than Cu+



122.

Which of the following does not give oxygen on heating?

  • KClO3

  • Zn(ClO3)2

  • K2Cr2O7

  • (NH4)2Cr2O7



123.

A magnetic moment of 1.73 BM will be shown by one among the following

  • [Cu(NH3)4]2+

  • [Ni(CN)4]2-

  • TiCl4

  • [CoCl6]4-



Short Answer Type

124.

Explain briefly the cause of Lanthanoid contraction.



Multiple Choice Questions

125.

Assertion: Cuprous ion (Cu+) is colorless whereas cupric ion (Cu2+) is blue in the aqueous solution.
Reason: Cuprous ion (Cu+) has unpaired electrons while cupric ion (Cu2+) does not.

  • If both assertion and reason are true and reason is a correct explanation of the assertion.

  • If both the assertion and reason are true but the reason is not a correct explanation of the assertion.

  • If the assertion is true but the reason is false.

  • If both the assertion and reason are false.



126.

The electronic configuration of Cu is

  • [Ne] 3s2, 3p6, 3d9, 4s2

  • [Ne] 3s2, 3p6, 3d10, 4s1

  • [Ne] 3s2, 3p6, 3d3, 3d9, 4s2, 4p6

  • [Ne] 3s2, 3p6, 3d5, 4s2, 4p4



127.

Which ofthe following lanthanoid ions is diamagnetic?
(At. nos. Ce = 58, Sm = 62, Eu = 63, Yb= 70)

  • Ce2+

  • Sm2+

  • Eu2+

  • Yb2+



128.

Which of the following compound is not coloured?

  • Na2[CuCl4]

  • Na2[CdCl4]

  • K4[Fe(CN)6]

  • K3[Fe(CN)6]



129.

The stable bivalency of Pb and trivalencey of Bi is:

  • due to d contraction in Pb and Bi

  • due to relativistic contraction of the 6s orbitals of Pb and Bi, leading to inert pair effect

  • due to screening effect

  • due to the attainment of noble liquid configuration



130.

Platinum, palladium and iridium are called noble metals because:

  • Alfred Nobel discovered them

  • they are shining lustrous and pleasing to look at

  • they are found in native state

  • they are inert towards many common reagents



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