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CBSE

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Chemistry
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NEET Chemistry : Thermodynamics

Multiple Choice Questions

111.

Which one of the following has S° greater than zero?

  • CaO(s) + CO2(g)  CaCO3(s)

  • NaCl(aq) NaCl(s)

  • NaNO3(s)  Na+(aq) + NO3-(aq)

  • N2(g) + 3H2(g)  2NH3(g)



112.

The potential energy diagram for a reaction R → P is given in the figure. H ° of the reaction corresponds to the energy

  • a

  • b

  • c

  • a + b



113.

Assertion : First ionization energy for nitrogen is lower than oxygen.

Reason : Across a period effective nuclear charge decreases.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.



114.

For the reaction of one mole of zinc dust with one mole of sulphuric acid in a bomb calorimeter, U and w corresponds to

  • U < 0, w = 0

  • U < 0, w < 0

  • U > 0, w = 0

  • U > 0, w > 0



115.

How much energy is released when 6 moles of octane is burnt in air? Given Hf° for CO2(g) , H2O(g) and C8H18(l)  respectively are - 490, -240 and +160 kJ/mol.

  • -6.2 kJ

  • -37.4 kJ

  • -35.5 kJ

  • -20.0 kJ



116.

Of the following which change will shift the reaction towards the product?

I2(g) 2I(g), Hf° (298K) = +150kJ

  • Increase in concentration of I

  • Decrease in concentration of I2

  • Increase in temperature

  • Increase in total pressure



117.

Assertion : Water in liquid state is more stable than ice at room temperature.

Reason : Water in liquid form has higher entropy than ice.

  • If both assertion and reason are true and reason is the correct explanation of the assertion.

  • If both assertion and reason are true but reason is not the correct explanation of the assertion.

  • If assertion is true, but reason is false.

  • Both assertion and reason are false statements.



118.

For the equilibrium H2O(l)  H2O(g) at 1 atm and 298K.

  • standard free energy change is equal to zero (G°= 0)

  • free energy change is less than zero (G° < 0)

  • standard free energy change is less than zero (G°< 0)

  • standard free energy change is greater than zero (G° > 0).



119.

The heat of neutralization of a strong base and a strong acid is 57 kJ. The heat released when 0.5 mole of HNO3 solution is added to 0.20 moles of NaOH solution, is :

  • 11.4 kJ

  • 34.7 kJ

  • 23.5 kJ

  • 58.8 kJ



120.

One gram sample of NH4NO3 is decomposed in a bomb calorimeter. The temperature of the calorimeter increases by 6.12 K. The heat capacity of the system is 1.23 kJ/g/deg. What is the molar heat of decomposition for NH4NO3 ?

  • -7.53 kJ/mol

  • -398.1 kJ/mol

  • -16.1 kJ/mol

  • -602 kJ/mol



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