Arrange the following in increasing order of their basic strength in aqueous solution:
CH3NH2, (CH3)3N, (CH3)2NH
18 g of glucose, C6H12O6 (Molar Mass = 180 g mol-1) is dissolved in 1 kg of water in a saucepan. At what temperature will this solution boil?
(Kb for water = 0.52 K kg mol-1, boiling point of pure water = 373.15 K)
The conductivity of 0.20 M solution of KCl at 298 K is 0.025 S cm-1. Calculate its molar conductivity?
Write the dispersed phase and dispersion medium of the following colloidal systems:
(i) Smoke (ii) Milk
What are lyophilic and lyophobic colloids? Which of these sols can be easily coagulated on the addition of small amounts of electrolytes?
Lyophilic colloids: It is made up of two words; ‘Lyo’ meaning liquid and ‘Phillic’ meaning loving, so those colloids which are attracted by the liquid (solvent), are called as lyophilic colloids. These are also called reversible sols. These are quite stable and cannot be easily coagulated. Example are Sols of organic substances like gelatin, gum, starch and proteins
Lyophobic colloids: It is made up of two words; ‘Lyo’ meaning liquid and ‘Phobic’ meaning repelling, so those colloids which are repelled by the liquid ( solvent), are called as lyophobic colloids. These are also called irreversible sols and these are unstable and can be easily coagulated due to lack of protecting layer around charged colloidal particles, they easily form a cluster. Hence, they got easily coagulated on the addition of small amount of electrolyte. Examples are Sols of inorganic substances like Arsenic (As2S3), Iron (Fe(OH)3) and Platinum.
Write the differences between physisorption and chemisorption with respect to the following:
(i) Specificity
(ii) Temperature dependence
(iii) Reversibility and
(iv) Enthalpy change
Which solution is used for the leaching of silver metal in the presence of air in the metallurgy of silver?