Which of the following is a more stable complex and why?
(i) [Co(NH3)6]3+
(ii) [Co(en)3]3+
An element with density 11.2 g cm-3 forms a f.c.c. lattice with edge length of 4 x10-8
Calculate the atomic mass of the element. (Given: NA = 6.022x 10-23 (mol-1)
Density, d = 11.2 g cm-3
Edge length, a = 4x10-8 cm
Avogadro number, NA = 6.022x1023 mol-1
Number of atoms present per unit cell, Z (fcc) = 4
We know for a crystal system,
Thus, the atomic mass of the element is 107.91 g.
Examine the given defective crystal:
Answer the following questions:
(i) What type of stoichiometric defect is shown by the crystal?
(ii) How is the density of the crystal affected by this defect?
(iii) What type of ionic substances shows such defect?
Calculate the mass of compound (molar mass = 256 g mol-1) to be dissolved in 75 of benzene to lower its freezing point by 0.48 K (Kf= 5.12 kg mol-1 )
Outline the principles behind the refining of metals by the following methods:
Zone refining method
Outline the principles behind the refining of metals by the following methods:
Chromatographic method