Define limiting molar conductivity. Why conductivity of an elect

Subject

Chemistry

Class

CBSE Class 12

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 Multiple Choice QuestionsShort Answer Type

1.

Out of BaCl2 and KCl, which one is more effective in causing coagulation of a negatively charged colloidal Sol? Give reason.

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2.

What is the formula of a compound in which the element Y forms ccp lattice and atoms of X occupy 1/3rd of tetrahedral voids?

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3.

What is the basicity of H3PO4?

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4.

 What is meant by positive deviations from Raoult's law? Give an example. What is the sign of mixH for positive deviation?

OR

Define azeotropes. What type of azeotrope is formed by positive deviation from Raoult's law? Give an example.

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5.

Following reactions occur at cathode during the electrolysis of aqueous silver chloride solution:


Ag+ (aq) + e-  →  Ag(s)          E° = +0.80 V

 H+ (aq) + e-   → 1/2 H2 (g)     E° = 0.00 V

 On the basis of their standard reduction electrode potential (E°) values, which reaction is feasible at the cathode and why?

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6.

Define limiting molar conductivity. Why conductivity of an electrolyte solution decreases with the decrease in concentration?


The limiting molar conductivity of an electrolyte is defined as its molar conductivity when the concentration of the electrolyte in the solution approaches zero.

The conductivity of an electrolyte solution is the conductance of ions present in a unit volume of the solution. The number of ions (responsible for carrying current) decreases when the solution is diluted or the concentration is decreased. As a result, the conductivity of an electrolyte solution decreases with the decrease in concentration.

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7.

What are the transition elements? Write two characteristics of the transition elements ?

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8.

Write down the IUPAC name of the following complex:


[Cr(NH3)2Cl2(en)]Cl    (en = ethylenediamine)

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9.

Write the formula for the following complex:


Pentaamminenitrito-o-Cobalt (III)

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10.

Draw the geometrical isomers of complex [Pt(NH3)2Cl2]? 

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