How can the following conversions be brought about:
(i) Acetic acid to methyl cyanide.
(ii) Acetaldehyde to formaldehyde.
(iii) Nitrobenzene to 2, 4, 6 tribromoaniline.
The deficiency of which vitamin will cause the following diseases:
(i) Scurvy
(ii) Haemorrhages
Give one chemical test to distinguish between the following pairs of compounds:
(i) Ethanol and 2 propanol.
(ii) Aniline and ethylamine
Give balanced equations for the following reactions:
(i) Acetaldehyde is heated with hydroiodic acid in the presence of red phosphorous.
(ii) Calcium acetate is subjected to dry distillation.
(iii) Sodium ethoxide is treated with ethyl bromide.
(iv) Benzaldehyde is treated with sodium bisulphite.
An organic compound A with molecular formula C7H8 on oxidation by chromylchloride in the presence of CCl4 gives a compound B which gives positive tollen’s test. The compound B on treatment with NaOH followed by acid hydrolysis gives two products C and D. C on oxidation gives B which on further oxidation gives D. The compound D on distillation with soda lime gives a hydrocarbon E. Below 60oC, concentrated nitric acid reacts with E in the presence of concentrated sulphuric acid forming a compound F. Identify the compounds A, B, C, D, E and F.
Identify the compounds from (A) to (F):
A = Toluene (or) C6H5CH3
B = Benzaldehyde (or) C6H5CHO
C = Benzyl Alcohol (or) C6H5CH2OH
D = Benzoic Acid (or) C6H5COOH
E = Benzene (or) C6H6
F = Nitrobenzene (or) C6H5NO2
Give balanced equations for the following name reactions:
(i) Clemmensen’s reduction.
(ii) Kolbe’s electrolytic reaction.
(iii) Balz-Schiemann’s reaction.
(i) What do you observe when glucose is treated with bromine water?
(ii) What is isoelectric point?
Answer the following:
(i) What is biuret test?
(ii) Write balanced equation for the formation of biuret.