Give balanced equations for the following name reactions: (i) C

Subject

Chemistry

Class

ICSE Class 12

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 Multiple Choice QuestionsShort Answer Type

31.

How can the following conversions be brought about:
(i) Acetic acid to methyl cyanide. 
(ii) Acetaldehyde to formaldehyde. 
(iii) Nitrobenzene to 2, 4, 6 tribromoaniline.

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32.

Identify the reagents A, B, C, D, E and F required for the following conversion:

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33.

The deficiency of which vitamin will cause the following diseases:
(i) Scurvy
(ii) Haemorrhages

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34.

Give one chemical test to distinguish between the following pairs of compounds: 
(i) Ethanol and 2 propanol.

(ii) Aniline and ethylamine

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35.

Write the structures of all enantiomers possible for lactic acid.

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36.

Give balanced equations for the following reactions: 
(i) Acetaldehyde is heated with hydroiodic acid in the presence of red phosphorous.
(ii) Calcium acetate is subjected to dry distillation.
(iii) Sodium ethoxide is treated with ethyl bromide.
(iv) Benzaldehyde is treated with sodium bisulphite.

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37.

An organic compound A with molecular formula C7H8 on oxidation by chromylchloride in the presence of CCl4 gives a compound B which gives positive tollen’s test. The compound B on treatment with NaOH followed by acid hydrolysis gives two products C and D. C on oxidation gives B which on further oxidation gives D. The compound D on distillation with soda lime gives a hydrocarbon E. Below 60oC, concentrated nitric acid  reacts with E in the presence of concentrated sulphuric acid forming a compound F. Identify the compounds A, B, C, D, E and F.

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38.

Give balanced equations for the following name reactions: 
(i) Clemmensen’s reduction.
(ii) Kolbe’s electrolytic reaction.
(iii) Balz-Schiemann’s reaction.


straight i right parenthesis space Clemmensen apostrophe straight s space reduction

CH subscript 3 CHO space plus 4 left parenthesis straight H right parenthesis space rightwards arrow from Conc. space HCl to Zn divided by Hg of space CH subscript 3 minus CH subscript 3 space plus straight H subscript 2 straight O

ii right parenthesis space Kolbe apostrophe straight s space electrolytic space reaction

2 CH subscript 3 space COOK space rightwards harpoon over leftwards harpoon space 2 CH subscript 3 COO to the power of minus space plus 2 straight K to the power of plus
2 straight H subscript 2 straight O space rightwards harpoon over leftwards harpoon space 2 straight H to the power of plus space plus 2 OH to the power of plus

at space anode space colon space 2 CH subscript 3 COO to the power of minus minus 2 straight e rightwards arrow space straight C subscript 2 straight H subscript 6 space plus CO subscript 2
at space cathode space 2 straight H to the power of plus space plus 2 straight e space rightwards arrow straight H subscript 2
iii) Balz-schiemann's reaction
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39.

(i) What do you observe when glucose is treated with bromine water? 
(ii) What is isoelectric point?

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40.

Answer the following:
(i) What is biuret test?
(ii) Write balanced equation for the formation of biuret.

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