(i) What do you observe when glucose is treated with bromine wat

Subject

Chemistry

Class

ICSE Class 12

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 Multiple Choice QuestionsShort Answer Type

31.

How can the following conversions be brought about:
(i) Acetic acid to methyl cyanide. 
(ii) Acetaldehyde to formaldehyde. 
(iii) Nitrobenzene to 2, 4, 6 tribromoaniline.

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32.

Identify the reagents A, B, C, D, E and F required for the following conversion:

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33.

The deficiency of which vitamin will cause the following diseases:
(i) Scurvy
(ii) Haemorrhages

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34.

Give one chemical test to distinguish between the following pairs of compounds: 
(i) Ethanol and 2 propanol.

(ii) Aniline and ethylamine

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35.

Write the structures of all enantiomers possible for lactic acid.

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36.

Give balanced equations for the following reactions: 
(i) Acetaldehyde is heated with hydroiodic acid in the presence of red phosphorous.
(ii) Calcium acetate is subjected to dry distillation.
(iii) Sodium ethoxide is treated with ethyl bromide.
(iv) Benzaldehyde is treated with sodium bisulphite.

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37.

An organic compound A with molecular formula C7H8 on oxidation by chromylchloride in the presence of CCl4 gives a compound B which gives positive tollen’s test. The compound B on treatment with NaOH followed by acid hydrolysis gives two products C and D. C on oxidation gives B which on further oxidation gives D. The compound D on distillation with soda lime gives a hydrocarbon E. Below 60oC, concentrated nitric acid  reacts with E in the presence of concentrated sulphuric acid forming a compound F. Identify the compounds A, B, C, D, E and F.

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38.

Give balanced equations for the following name reactions: 
(i) Clemmensen’s reduction.
(ii) Kolbe’s electrolytic reaction.
(iii) Balz-Schiemann’s reaction.

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39.

(i) What do you observe when glucose is treated with bromine water? 
(ii) What is isoelectric point?


left parenthesis straight i right parenthesis space Decolourises space bromie space water colon space left parenthesis Red space colour space of space bromine space water space disappear right parenthesis space

stack CH subscript 2 OH space left parenthesis CHOH right parenthesis subscript 4 CHO with gllucose below space rightwards arrow from increment to Br subscript 2 divided by straight H subscript 2 straight O of stack space CH subscript 2 OH left parenthesis CHOH right parenthesis subscript 4 COOH with Gluconic space acid below

ii)  Isoelectric point – At a particular pH of a solution the amino acid molecule should not migrate to either electrode and should exist as a neutral dipolar ion. This pH is known as isoelectric point
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40.

Answer the following:
(i) What is biuret test?
(ii) Write balanced equation for the formation of biuret.

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