Heat liberated with 100 mL of 1 N NaOH is neutralised by 300 mL o

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

1.

A colourless crystalline salt 'x' is soluble in dilute HCl. On adding NaOH solution, it gives a white precipitate which is insoluble in excess of NaOH. 'x' is

  • Al2(SO4)3

  • ZnSO4

  • MgSO4

  • SnCl2


2.

Which metal is used to make alloy steel for armour plates, safes and helmets?

  • Al

  • Mn

  • Cr

  • Pb


3.

Enthalpy of formation of HF and HCl are -161 kJ and -92 kJ respectively. Which of the following statements is incorrect?

  • HCl is more stable than HF

  • HF and HCl are exothermic compounds

  • The affinity of fluorine to hydrogen is greaterthan the affinity of chlorine to hydrogen

  • HF is more stable than HCl


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4.

Heat liberated with 100 mL of 1 N NaOH is neutralised by 300 mL of 1 N HCl

  • 11.56 kJ

  • 5.73 kJ

  • 22.92 kJ

  • 17.19 kJ


B.

5.73 kJ

The molarity and normality are same in case of NaOH and HCl because the acidity and basicity of these are one and one respectively,

Since, number of moles = molarity × volume (l)

 Number of moles of NaOH solution = 100 × 11000 = 0.1

And number of moles of HCl solution = 300 × 11000 = 0.3

Hence, 0.1 mole NaOH is neutralised by 0.1 mole HCl. We know that heat of neutralisation of 1 mole HCl and 1 mole NaOH is 57.3 kJ. Hence, heat of neutralisation of 0.1 mole HCl  and 0.1 mole

NaOH will be = 57.3 × 0.1 = 5.73 kJ


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5.

The enthalpies of formation of Al2O3 and Cr2O3 are -1596 kJ and -1134 kJ respectively. H for the reaction,

2Al + Cr2O3  → 2Cr+ Al2O3 is

  • -2730 kJ

  • -462 kJ

  • -1365 kJ

  • +2730 kJ


6.

The gaseous reaction

A + B  2C + D + Q is most favoured at

  • low temperature and high pressure

  • high temperature and high pressme

  • high temperature and low pressure

  • low temperature and low pressure


7.

The volume of water to be added to N2 to prepare 500 mL of N10 solution is

  • 450 mL

  • 100 mL

  • 45 mL

  • 400 mL


8.

The equivalent weight of a certain trivalent element is 20. Molecular weight of its oxide is

  • 152

  • 56

  • 168

  • 68


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9.

Solubility product of a salt AB is 1 × 10-8 in a solution in which concentration of A is 10-3 M. The salt will precipitate when the concentration of B becomes more than

  • 10-4 M

  • 10-7 M

  • 10-6 M

  • 10-5 M


10.

The percentage s-character of the hybrid orbitals in methane, ethene and ethyne are respectively

  • 25, 33, 50

  • 25, 50, 75

  • 50, 75, 100

  • 10, 20, 40


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