The relative lowering of vapour pressure of a dilute aqueous solution containing nonvolatile solute is 0.0125. The molality of the solution is about
0.70
0.50
0.90
0.80
If the elevation in boiling point of a solution of 10g of solute (mol. wt. = 100) in 100g of water is ΔTb, the ebullioscopic constant of water is
100Tb
ΔTb
10Tb
10
An alloy of Pb-Ag weighing 1.08g was dissolved in dilute HNO3 and the volume made to 100 mL. A silver electrode was dipped in the solution and the emf of the cell set up Pt(s), H2(g)|H+(1M) || Ag+(aq)|Ag(s) was 0.62V. If E°cell= 0. 80V what is the percentage of Ag in the alloy? [At 25°C, RT IF= 0.06].
50
1
10
25
The standard oxidation potentials of Zn, Cu, Ag and Ni electrodes are +0.76, 0.34, - 0.80 and +0.25 V respectively. Which of the following reaction will provide maximum voltage?
Cu + 2Ag+(aq) → Cu+2 (aq) +2Ag
Zn + 2Ag+(aq) → Zn2+(aq) + 2Ag
H2 + Ni2+ (aq) → 2H+(aq) + Ni
Zn + Cu2+(aq) → Zn2+(aq) + Cu