The pKa of a weak acid (HA) is 4.5. The pOH of an aqueous buffered solution of HA in which 50% of the acid is ionized is
4.5
2.5
9.5
9.5
Assuming that water vapour is an ideal gas, the internal energy change(∆U) when 1 mol of water is vapourised at 1 bar pressure and 100°C, (Given: Molar enthalpy of vapourisation of water at 1 bar and 373 K = 41 kJ mol-1 and R = 8.3 J mol–1K–1 will be) –
4.100 kJ mol–1
3.7904 kJ mol–1
37.904 kJ mol–1
37.904 kJ mol–1
Which of the following sets of quantum numbers represents the highest energy of an atom?
n = 3, l = 1, m = 1, s = +½
n = 3, l = 2, m = 1, s = +½
n = 4, l = 0, m = 0, s = +½
n = 4, l = 0, m = 0, s = +½
Which of the following hydrogen bonds is the strongest?
O – H …… N
F – H …… F
O – H ….. O
O – H ….. O
In the reaction,
2Al(s) + 6HCl(aq) → 2Al3+ (aq) + 6Cl¯(aq) + 3H2(g)
6L HCl(aq) is consumed for every 3L H2(g) produced
33.6 L H2(g) is produced regardless of temperature and pressure for every mole Al that reacts
67.2 L H2(g) at STP is produced for every mole Al that reacts
67.2 L H2(g) at STP is produced for every mole Al that reacts
Regular use of which of the following fertilizers increases the acidity of soil ?
Potassium nitrate
Urea
Superphosphate of lime
Superphosphate of lime
Identify the correct statement regarding a spontaneous process –
For a spontaneous process in an isolated system, the change in entropy is positive
Endothermic processes are never spontaneous
Exothermic processes are always spontaneous
Exothermic processes are always spontaneous
The charge/size ratio of a cation determines its polarizing power. Which one of the following sequences represents the increasing order of the polarizing power of the cationic species, K+, Ca2+, Mg2+, Be2+?
Mg2+ < Be2+ < K+ < Ca2+
Be2+ < K+ < Ca2+ < Mg2+
K+ < Ca2+ < Mg2+ < Be2+
K+ < Ca2+ < Mg2+ < Be2+
In the conversion of limestone to lime, CaCO3(s) → CaO(s) + CO2(g) the values of ∆Hº and ∆Sº are + 179.1 kJ mol–1 and 160.2 J/K respectively at 298K and 1 bar. Assuming that ∆Hº and ∆Sº do not change with temperature, temperature above which conversion of limestone to lime will be spontaneous is
1008 K
1200 K
845 K
845 K
The energies of activation for forward and reverse reactions for A2 + B2 ⇌ 2AB are 180 kJ mol–1 and 200 kJ mol–1 respectively. The presence of a catalyst lowers the activation energy of both (forward and reverse) reactions by 100 kJ mol–1. The enthalpy change of the reaction (A2 + B2 → 2AB) in the
presence of catalyst will be (in kJ mol–1) –
300
120
280
280