JEE Chemistry Solved Question Paper 2010 | Previous Year Papers | Zigya

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

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1.

The wave number of the spectral line in the emission spectrum of hydrogen will be equal to 89 times the rydberg's constant if the electron jumps from

  • n =3 to n =1

  • n = 10 to n=1

  • n=9 to n=1

  • n = 2 to n=1


2.

Consider the following gaseous equilibria with equilibrium constants K1 and K2 respectively.

SO2(g) + 12O2(g) SO3(g)2SO3(g)  2SO2 (g) + O2(g)The equilibrium constants are related as

  • K12 = 1K2

  • 2K1= K22

  • K2=2K12

  • K22=1K1


3.

Enthalpy of vaporization of benzene is + 35.3 kJ mol-1at its boiling point, 80C. The entropy change in the transition of the vapour to liquid at its boiling point in [JK-1mol-1] is

  • -441

  • -100

  • +441

  • +100


4.

Which one of the following conversions involve change in both hybridisation and shape?

  • CH4 → C2H6

  • NH3 → NH4+

  • BF3 → BF4-

  • H2O → H3O+


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5.

In the reversible reaction,

A(s) + B(g) ⇌ C (g) + D(g) ΔG° = -350kJ

Which one of the following statements is true?

  • The entropy change is negative

  • Equilibrium constant is greater than one

  • The reaction should be instantaneous

  • The reaction is thermodynamically not feasible


6.

The amount of heat evolved when 500 cm3 of 0.1 M HCl is mixed with 200 cm3 of 0.2 M NaOH is

  • 2.292 kJ

  • 1.292 kJ

  • 0.292 kJ

  • 3.392 kJ


7.

During the adsorption of krypton on activated charcoal at low temperature.

  • ΔH > 0 and ΔS < 0

  • ΔH < 0 and ΔS < 0

  • ΔH > 0 and ΔS > 0

  • ΔH < 0 and ΔS < 0


8.

The set of quantum numbers for the outermost electron for copper in its ground state is

  • 4, 1, 1 +1/2

  • 3, 2, 2, +1/2

  • 4, 0, 0, +1/2

  • 4, 2, 2, +1/2


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9.

Peroxide ion ......
(i) has five completely filled antibonding molecular orbitals
(ii) is diamagnetic
(iii) has bond order one
(iv) is isoelectronic with neon
Which one of these is correct?

  • (ii) and (iii)

  • (i), (ii) and (iv)

  • (i), (ii) and (iii)

  • (i) and (iv)


10.

A mixture of CaCl2 and NaCl weighing 4.44 g is treated with sodium carbonate solution to precipitate all the Ca2+ ions as calcium carbonate. The calcium carbonate so obtained is heated strongly to get 0.56 g of Cao. The percentage of NaCl in the mixture (atomic mass of Ca = 40) is

  • 75

  • 30.6

  • 25

  • 69.4


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