The wave number of the spectral line in the emission spectrum of hydrogen will be equal to times the rydberg's constant if the electron jumps from
n =3 to n =1
n = 10 to n=1
n=9 to n=1
n = 2 to n=1
Enthalpy of vaporization of benzene is + 35.3 kJ mol-1at its boiling point, 80C. The entropy change in the transition of the vapour to liquid at its boiling point in [JK-1mol-1] is
-441
-100
+441
+100
Which one of the following conversions involve change in both hybridisation and shape?
CH4 → C2H6
NH3 → NH
BF3 → BF
H2O → H3O+
In the reversible reaction,
A(s) + B(g) C (g) + D(g) ΔG° = -350kJ
Which one of the following statements is true?
The entropy change is negative
Equilibrium constant is greater than one
The reaction should be instantaneous
The reaction is thermodynamically not feasible
The amount of heat evolved when 500 cm3 of 0.1 M HCl is mixed with 200 cm3 of 0.2 M NaOH is
2.292 kJ
1.292 kJ
0.292 kJ
3.392 kJ
During the adsorption of krypton on activated charcoal at low temperature.
ΔH > 0 and ΔS < 0
ΔH < 0 and ΔS < 0
ΔH > 0 and ΔS > 0
ΔH < 0 and ΔS < 0
The set of quantum numbers for the outermost electron for copper in its ground state is
4, 1, 1 +1/2
3, 2, 2, +1/2
4, 0, 0, +1/2
4, 2, 2, +1/2
Peroxide ion ......
(i) has five completely filled antibonding molecular orbitals
(ii) is diamagnetic
(iii) has bond order one
(iv) is isoelectronic with neon
Which one of these is correct?
(ii) and (iii)
(i), (ii) and (iv)
(i), (ii) and (iii)
(i) and (iv)
A mixture of CaCl2 and NaCl weighing 4.44 g is treated with sodium carbonate solution to precipitate all the Ca2+ ions as calcium carbonate. The calcium carbonate so obtained is heated strongly to get 0.56 g of Cao. The percentage of NaCl in the mixture (atomic mass of Ca = 40) is
75
30.6
25
69.4