A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to 375 mL at a constant temperature of 37.00C. As it does so, it absorbs 208J of heat. The values of q and w for the process will be:(R = 8.314 J/mol K) ( ln 7.5 = 2.01)
q =+208J, W = - 208 J
q =-208 J, W =-208 J
q=-208J, W = +208 J
q=-208J, W = +208 J
For the gaseous state, if most probable speed is denoted by C*, average speed by C and mean square speed by C, then for a large number of molecules the ratios of these speeds are:
A gaseous hydrocarbon gives upon combustion 0.72 g of water and 3.08 g of CO2.The empirical formula of the hydrocarbon is
C2H4
C3H4
C6H5
C6H5
In which of the following pairs of molecules/ions, both the species are not likely exist?
Which of the following exists as covalent crystals in the solid state?
Iodine
Silicon
Sulphur
Sulphur
B.
Silicon
D.
Sulphur
Silicon (Si) – covalent solid
Sulphur (S8) – molecular solid
Phosphorous (P4) – Molecular solid
Iodine (I2) – Molecular solid
Which of the following represents the correct order of increasing first ionisation enthalpy for Ca, Ba, S, Se and Ar?
Ca <S<Ba<Se<Ar
S< Se<Ca<Ba< Ar
Ba< Ca<Se< S< Ar
Ba< Ca<Se< S< Ar
Energy of an electron is given by
E =- 2.178 x 10-18 J
Wavelength of light required to excite an electron in a hydrogen atom from level n =1 to n=2 will be (h=6.62 x 1034 Js and c = 3.0 x 108 ms-1)
1.214 x 10-7 m
2.816 x 10-7 m
6.500 x 10-7 m
6.500 x 10-7 m
The first ionisation potential of Na is 5.1 eV. The value of electron gain enthalpy of Na+ will be
-2.55 eV
-5.1 eV
-10.2 eV
-10.2 eV
Stability of the species Li2, Li2− and Li2+ increases in the order of:
Li2 < Li2+ < Li2-
Li2− < Li2+ < Li2
Li2< Li2− < Li2+
Li2< Li2− < Li2+
Experimentally it was found that a metal oxide has formula M0.98O. Metal M, is present as M2+ and M3+ in its oxide. The fraction of the metal which exists as M3+ would be:
7.01%
4.08%
6.05%
6.05%