The geometrical and optical isomers of complex [Pt(NH3)(Br)(Cl)(P

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

11.

The solubility of Al(OH)3 is 'S' mol L-1. The solubility product will be

  • S2

  • S3

  • 27 S4

  • 27 S3


12.

When 1 M H2SO4 is completely neutralized by NaOH, the heat liberated is 114.64 kJ. What is the enthalpy of neutralization?

  • + 114.64 kJ

  • -114.64 kJ

  • -57.32 kJ

  • + 57.32 kJ


13.

 for the reaction

CO (g) +  O2 (g)  CO2 (g) is

  • RT

  • 1RT

  • RT

  • 1RT


14.

A particle 'A' moving with a certain velocity has the de-Broglie wavelength 1 Å. For a particle 'B' with mass 25% of 'A' and velocity 75% of 'A'. The de-Broglie wave length of 'B' will be

  • 3 Å

  • 5.33 Å

  • 6.88 Å

  • 0.68 Å


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15.

The reaction,

3ClO- (aq) → ClO3- (aq) + 2Cl- (aq) is an example of

  • oxidation reaction

  • reduction reaction

  • disproportionation reaction

  • decomposition reaction


16.

Which compound is aromatic?


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17.

The geometrical and optical isomers of complex [Pt(NH3)(Br)(Cl)(Py)] respectively 

  • 2, 2

  • 0, 3

  • 2, 1

  • 3, 0


D.

3, 0

Isomerism which occurs due to different relative arrangements of ligands around central metal atom is known as geometrical isomerism. Complexes of formula MABCD may exist in three isomeric forms.

e.g. [Pt(NH3)(Br)(Cl)(Py)]

Square planar complexes do not show optical isomerison since they are not optically active as they have all the ligands and metal atoms in one plane, hence, it is a plane of symmetry.


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18.

One of the isomer of the 5th member of alkyne series is optically active. It is

  • 4-methyl pent-2-yne

  • 3-methyl pent-1-yne

  • 4-methyl pent-1-yne

  • 3, 3-dimethyl but-1-yne


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19.

The substance not likely to contain CaCO3 is

  • marble statue

  • calcined gypsum

  • sea shells

  • dolomite


20.

Schiff's nitrometre is filled with

  • mercury

  • water over mercury seal

  • KOH solution over mercury seal

  • toulene over mercury seal


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