Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

21.

If a LPG cylinder contains mixture of butane and isobutane, then the amount of oxygen that would be required for combustion of 1 kg of it will be

  • 2.50 × 103 gm

  • 4.50 × 103 gm

  • 180  × 103 gm

  • 3.58 × 103 gm


22.

The correct order of basic strength of the following are

  • 1 > 2 > 3 > 4

  • 4 > 2 > 3 > 1

  • 3 > 4 > 2 > 1

  • 3 > 2 > 4 > 1


23.

An organic compound C3H5Cl (A) when treated with magnesium in dry ether gives (B) which on treating with CO2 followed by acid hydrolysis gives C4H6O2 (C). (C) is also obtained on oxidation of a hydrocarbon (D) C8H12. Structure of A is

  • CH2=CH-CH2-Cl

  • CH2=C(Cl)-CH3

  • CH(Cl)=CH-CH3


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24.

Oxidation number of chlorine atom in Ca(OCl)Cl is

  • -1

  • +1, -1

  • 0

  • -1, 0


B.

+1, -1

In CaOCl2, according to the calculation, the oxidation states of both chlorine atoms are zero. But, it is their average oxidation state. In actual practice, the structure of CaOCl2 is ClO-Ca-Cl.

Thus, in CaOCl2, two types of anions ClO- and Cl- are present. Out of these, the oxidation state of Cl is - 1, but the oxidation state of chlorine in OCl- ion s + 1 as oxygen is more electronegative than chlorine, hence oxidation state of oxygen remains -2 while oxidation state of chlorine becomes +1.


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25.

The cumulated alkadiene is


26.

Which of the following compound is not aromatic?

  • 1, 3-cyclobutadene

  • Pyridine

  • Furan

  • Thiophene


27.

The structure shows

  • geometrical isomerism

  • optical isomerism

  • geometrical and optical isomerism

  • tautomerism


28.

What is the correct IUPAC name of

  • 4-methoxy-2-nitrobenzaldehyde

  • 4-formyl-3-nitroanisole

  • 4-methoxy-6-nitrobenzaldehyde

  • 2-formyl-5-methoxynitrobenzene


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29.

In Kjeldahl's method of estimation of nitrogen, CuSO4 act as

  • oxidising agent

  • reducing agent

  • catalytic agent

  • hydrolysis agent


30.

The pairs of compounds which cannot exists together in a solution is

  • NaHCO3 and NaOH

  • Na2CO3 and NaOH

  • Na2CO3 and NaHCO3

  • NaHCO3 and NaCl


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