A positive carbylamine test is given by
I. N, N-dimethylaniline
II. 2, 4-dimethylamine
III. N-methyl-o-methylaniline
IV. p-methylbenzyl amine
(II) and (IV)
(I) and (IV)
(II) and (III)
(I) and (II)
Identify the final product B of the reaction
C6H5COOH + NaHO3 → gas (A) (B)
Here, = C14
H3COOH
C6H5OOH
CH3OOH
HOOCH3
CH3CHO + HCHO
The structure of the compound B is
CH2=CH-CH(OH)-COOH
CH2=CH-CH(CN)-OH
CH3-CH2-CN(CN)OH
CH3--COOH
Phenol + CCl4 + KOH → X;
Which of the following statement is true for X?
It gives effervescence with NaHCO3
Gives silver mirror with Tollen's reagent
Does not give the red colour with FeCl3
All of the above
A.
It gives effervescence with NaHCO3
The given reaction is Reimer-Tiemann reaction.
Among the given statements, statement a is true for X. Salicylic acid gives effervescence with NaHCO3, which is a characteristic feature of carboxylic acid. Thus, it ensures the presence of a carboxylic group in it.