Among the following structures the one which is not a resonating structure of others is
I
II
III
IV
Among the following compounds, the one(s) that gives (give) effervescence with aqueous NaHCO3 solution is (are)
(CH3CO)2 O CH3COOH PhOH CH3COCHO
I II III IV
I and II
I and III
Only II
I and IV
The order of decreasing ease of abstraction of hydrogen atoms in the following molecules
Ha > Hb > Hc
Ha > Hc > Hb
Hb > Ha > Hc
Hc > Hb > Ha
B.
Ha > Hc > Hb
Abstraction of (Ha) hydrogen atom results in the formation of 3° allylic carbocation whereas abstraction of He gives 2° allylic carbocation (which is less stable as compared to former one). However, abstraction of Hb gives only a 2° carbocation which is less stable as compared to former two. More the stability of generated carbocation, higher is the tendency of abstraction of hydrogen. Thus. the order of decreasing ease of abstraction of hydrogen atoms from the given molecule is
Ha > Hc > Hb
Among the following statements about the molecules X and Y, the one(s) which correct is (are)
X and Y are diastereomers
X and Y are enantiomers
X and Y are both aldohexoses
Xis a D-sugar and Y is an L-sugar
The rate of a certain reaction is given by, rate = k [H+]n. The rate increases 100 times when the pH changes from 3 to 1. The order (n) of the reaction is
2
0
1
1.5
If Cl2 is passed through hot aqueous NaOH, the products formed have Cl in different oxidation states. These are indicated as
-1 and +1
-1and +5
+1 and +5
-1and +3