The sodium extract of an organic compound on acidification with a

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

11.

An f-shell containing 6 unpaired electrons can exchange

  • 6 electrons

  • 9 electrons

  • 12 electrons

  • 15 electrons


12.

Which sequence of reactions shows correct chemical relation between sodium and its compounds?

  • Na + O2  Na2O HCl(aq)NaClCO2Na2CO3Na

  • NaO2Na2OH2ONaOHCO2Na2CO3Na

  • Na+H2O NaOHHClNaClCO2Na2CO2Na

  • Na+H2O NaOH CO2Na2CO3HClNaCl(molten) ElectrolysisNa


13.

Which of the following compounds cannot be prepared singly by the Wurtz reaction?

  • C2H6

  • (CH3)2CHCH3

  • CH3CH2CH2CH3

  • All of the above can be prepared


14.

Which of the following oxides is strongly basic?

  • TI2O

  • B2O3

  • Al2O3

  • Ga2O3


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15.

Among the following the strongest nucleophile is

  • C2H5SH

  • CH3COO-

  • CH3NH2

  • NCCH2-


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16.

The sodium extract of an organic compound on acidification with acetic acid and addition of lead acetate solution gives a black precipitate. The organic compound contains

  • nitrogen

  • halogen

  • sulphur

  • phosphorus


C.

sulphur

The sulphur containing organic compounds when fused with sodium metal give Na2S which react with lead acetate and forms black ppt. of PbS.

Na2S + (CH3COO)2Pb  PbSBlackppt + 2CH3COONa


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17.

The equivalent conductivity of a solution containing 2.54 g of CuSO4, per L is 91.0 W-1 cm2eq-1. Its conductivity would be

  • 2.9 × 10-3Ω-1cm-1

  • 1.8 × 10-2 Ω-1 cm-1

  • 2.4 × 10-4 Ω-1cm-1

  • 3.6 × 10-3Ω-1cm-1


18.

The half-life of two samples are 0.1 and 0.8 s. Their respective concentration are 400 and 50 respectively. The order of the reaction is

  • 0

  • 2

  • 1

  • 4


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19.

Purest form of iron is

  • pig iron

  • wrought iron

  • cast iron

  • steel


20.

Which has the smallest size?

  • Na+

  • Mg2+

  • Al3+

  • P5+


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