Which one of the following is more readily hydrolysed by SN1 mech

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

11.

In a reaction, A + B C + D, D, 40% of B has reacted at equilibrium, when 1 mole of A was heated with 1 mole of B in a 10 L closed vessel. The value of Kc is

  • 0.44

  • 0.18

  • 0.22

  • 0.36


12.

If the ionc product of Ni(OH)2 is 1.9× 10-15, the molar solubility of Ni(OH)in 1.0 M NaOH

  • 1.9 × 10-18 M

  • 1.9 × 10-13 M

  • 1.9 × 10-15 M

  • 1.9 × 10-15 M


13.

Which one of the following elements on doping with germanium, make it a p-type semiconductor?

  • Boron

  • Selenium

  • Arsenic

  • Germanium


14.

Which one of the following gives sooty flame on combustion?

  • C2H4

  • CH4

  • C2H6

  • C6H6


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15.

What is Z in the following reaction?

CH3-CH2-CO2NaNaOH/CaO Z

  • propane

  • n-butane

  • ethane

  • ethyne


16.

What are X and Y in the following reaction?

CF2Cl2 UV X + Y

  • CF2Cl, Cl

  • C2F4, Cl2

  • CFCl2, F

  • CCl2, F2


17.

Which one of the following elements reacts with steam?

  • C

  • Ge

  • Si

  • Sn


18.

Temporary hardness of water is removed in Clark's process by adding

  • caustic soda

  • calgon

  • borax

  • lime


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19.

Which one of the following correctly represents the variation of electronegatrvity (EN) with atomic number (Z) of group 13 elements?


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20.

Which one of the following is more readily hydrolysed by SN1 mechanism?

  • (C6H5)2C(CH3)Br

  • C6H5CH2Br

  • C6H5CH(CH3)Br

  • (C6H5)2CHBr


A.

(C6H5)2C(CH3)Br

The order of reactivity of halides towards SN1 reaction is benzyl> allyl>3°> 2°> 1°> Me.

Therefore, the order of hydrolysis by SN1 mechanism is


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