Which one of the following species acts as both Bronsted acid and

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

11.

The radius of which of the following orbit is same as that of the first Bohr's orbit of hydrogen atom?

  • Li2+ (n = 2)

  • Li2+ (n = 3)

  • Be3+ (n = 2)

  • He+ ( n = 2)


12.

Van der waals' real gas, acts as an ideal gas at which condition?

  • High temperature, low pressure

  • Low temperature, high pressure

  • High temperature, high pressure

  • Low temperature, low pressure


13.

Ionisation energy in group 1A varies in the decreasing order as

  • Li > Na > K > Cs

  • Na > Li > K > Cs

  • Li > Cs > K  Na

  • K > Cs > Na > Li


14.

Intramolecular hydrogen bond is present in

  • water

  • o-nitrophenol

  • p-nitrophenol

  • methylamine


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15.

Which one of the following species acts as both Bronsted acid and base?

  • H2PO2-

  • HPO32-

  • HPO42-

  • All of these


C.

HPO42-

HPO42- + H2O  H2PO4- + OH-HPO42- + H2O  PO43- + H3O+

H2PO2- is a conjugate base of H3PO2 (a monobasic acid) and does not give H+, H3PO32- is a conjugate base of H2PO3- and does not ionise further. Since, H3PO3 is a dibasic acid.


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16.

The reaction, SO2 + O2 → 2SO2 + Heat.

The equilibrium reaction proceeds in forward direction by

  • addition of O2

  • removal of O2

  • addition of inert gas

  • cannot proceed


17.

Which is soluble in NaNO3 and dil. HCl mixture and forming salt?

  • (CH3)3CNH2

  • (CH3)2CHNH2

  • (CH3)2NH

  • (CH3)3N


18.

An example of a non-stoichiometric compound is

  • PbO

  • NiO2

  • Al2O3

  • Fe3O4


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19.

Which of the following type of forces are present in vulcanised rubber?

  • Weakest intermolecular forces

  • Hydrogen bonding

  • Three dimensional network of bonds

  • Metallic bonding


20.

If  H(H2O) is -286.20 kJ mol-1, then  Hf°  (OH-) is

  • -228.88 kJ mol-1

  • +228.88 kJ mol-1

  • -343.52 kJ mol-1

  • +343.52 kJ mol-1


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