A stream of electrons from a heated filament was passed between

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

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1.

A stream of electrons from a heated filament was passed between two charged plates kept at a potential difference V esu. If e and m are charge and mass of an electron, respectively, then the value of h/λ (where λ is wavelength associated with electron wave) is given by:

  • 2meV

  • square root of mev
  • square root of 2 meV end root
  • square root of 2 meV end root


C.

square root of 2 meV end root

The relation between h/λ and energy is given as:

Applying de-Broglie wavelength and kinetic energy term in eV.

de-Broglie wavelength for an electron (λ) = h/p

⇒ p  = h/ λ       (i)
Kinetic energy of an electron = eV
As we know that,



From equations (i) and (ii), we get

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2.

The heats of combustion of carbon and carbon monoxide are −393.5 and −283.5 kJ mol−1, respectively. The heat of formation (in kJ) of carbon monoxide per mole is:

  • 676.5

  • -676.5

  • -110.5

  • -110.5

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3.

The species in which the N atom is in a state of sp hybridization is:

  • NO2-

  • NO3-

  • NO2

  • NO2

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4.

The equilibrium constant at 298 K for a reaction A+B ⇌ C+D is 100. If the initial concentration of all the four species were 1 M each, then equilibrium concentration of D (in mol L−1 ) will be:

  • 0.818

  • 1.818

  • 1.182

  • 1.182

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5.

Which of the following atoms has the highest first ionisation energy?

  • Na

  • K

  • Sc

  • Sc

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6.

Two closed bulbs of equal volume (V) containing an ideal gas initially at pressure pi and temperature T1 are connected through a narrow tube of negligible volume as shown in the figure below. The temperature of one of the bulbs is then raised to T2. The final pressure pf is:

  • 2 straight p subscript straight i open parentheses fraction numerator straight T subscript 1 over denominator straight T subscript 1 plus straight T subscript 2 end fraction close parentheses
  • 2 straight p subscript straight i open parentheses fraction numerator straight T subscript 2 over denominator straight T subscript 1 plus straight T subscript 2 end fraction close parentheses
  • 2 straight p subscript straight i space open parentheses fraction numerator straight T subscript 1 straight T subscript 2 over denominator straight T subscript 1 plus straight T subscript 2 end fraction close parentheses
  • 2 straight p subscript straight i space open parentheses fraction numerator straight T subscript 1 straight T subscript 2 over denominator straight T subscript 1 plus straight T subscript 2 end fraction close parentheses
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7.

The hottest region of Bunsen flame shown in the figure below is:


  • region 2

  • region 3

  • region 4

  • region 4

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8.

The distillation technique most suited for separating glycerol from spent-lye in the soap industry is:

  • fractional distillation

  • steam distillation

  • distillation under reduced pressure

  • distillation under reduced pressure

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9.

At 300 K and 1 atm, 15 mL of a gaseous hydrocarbon requires 375 mL air containing 20% O2 by volume for complete combustion. After combustion the gases occupy 330 mL. Assuming that the water formed is in liquid form and the volumes were measured at the same temperature and pressure, the formula of the hydrocarbon is:

  • C3H8

  • C4H8

  • C4H12

  • C4H12

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10.

Which one of the following statements about water is false?

  • Water can act both as an acid and as a base.

  • There is extensive intramolecular hydrogen bonding in the condensed phase.

  • Ice formed by heavy water sinks in normal water.

  • Ice formed by heavy water sinks in normal water.

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