A stream of electrons from a heated filament was passed between two charged plates kept at a potential difference V esu. If e and m are charge and mass of an electron, respectively, then the value of h/λ (where λ is wavelength associated with electron wave) is given by:
2meV
The heats of combustion of carbon and carbon monoxide are −393.5 and −283.5 kJ mol−1, respectively. The heat of formation (in kJ) of carbon monoxide per mole is:
676.5
-676.5
-110.5
-110.5
The species in which the N atom is in a state of sp hybridization is:
NO2-
NO3-
NO2
NO2
The equilibrium constant at 298 K for a reaction A+B ⇌ C+D is 100. If the initial concentration of all the four species were 1 M each, then equilibrium concentration of D (in mol L−1 ) will be:
0.818
1.818
1.182
1.182
Which of the following atoms has the highest first ionisation energy?
Na
K
Sc
Sc
C.
Sc
Order of first ionisation energy is Sc> Na > K > Rb. Due to poor shielding effect, removal of one electron from 4s orbital is difficult as compared to 3s-orbital.
Two closed bulbs of equal volume (V) containing an ideal gas initially at pressure pi and temperature T1 are connected through a narrow tube of negligible volume as shown in the figure below. The temperature of one of the bulbs is then raised to T2. The final pressure pf is:
The hottest region of Bunsen flame shown in the figure below is:
region 2
region 3
region 4
region 4
The distillation technique most suited for separating glycerol from spent-lye in the soap industry is:
fractional distillation
steam distillation
distillation under reduced pressure
distillation under reduced pressure
At 300 K and 1 atm, 15 mL of a gaseous hydrocarbon requires 375 mL air containing 20% O2 by volume for complete combustion. After combustion the gases occupy 330 mL. Assuming that the water formed is in liquid form and the volumes were measured at the same temperature and pressure, the formula of the hydrocarbon is:
C3H8
C4H8
C4H12
C4H12
Which one of the following statements about water is false?
Water can act both as an acid and as a base.
There is extensive intramolecular hydrogen bonding in the condensed phase.
Ice formed by heavy water sinks in normal water.
Ice formed by heavy water sinks in normal water.