Amongst the following, which should have the highest rms speed at the same temperature?
SO2
CO2
O2
H2
In which of the following mixed aqueous solutions, pH =pKa at equilibrium?
(1) 100 mL of 0.1 M CH3COOH +100mL 0.1 M CH3COONa.
(2) 100 mL of 0.1 M CH3COOH + 50 mL of 0.1 M NaOH.
(3) 100 mL of 0.1 M CH3COOH + 100 mL of 0.1 M NaOH.
(4) 100 mL of 0.1 M CH3COOH + 100 mL of 0.1 M NH3.
(1) is correct
(2) is correct
(3) is correct
Both (1) and (2) are correct
Which statement is not correct for ortho and para hydrogen?
They have different boiling points
Ortho-form is more stable than para-form
They differ in their nuclear spin
The ratio of ortho to para hydrogen changes with change in temperature
B.
Ortho-form is more stable than para-form
(i) Ortho and para hydrogens have different nuclear spin. In H2 molecule, two protons in two H atoms with parallel spin are called ortho-hydrogen.
Nucleus of hydrogen atom with same spin (ortho) and with opposite spin are called para-hydrogen.
Nucleus of hydrogen atom with different spin (para).
(ii) Ortho-hydrogen is more stable than para form at and above room temperature only, therefore para form always tends to revert in ortho-form. Thus, not correct.
(iii) The per cent composition of ortho and para changes with the temperature. Thus, their ratio also change.
(iv) They have slightly different boiling point.
Hence, (b) is the answer.
Ozonolysis of an alkene produces only one dicarbonyl compound. The structure of the alkene is
H3C - CH = CH - CH3
CH3 - CH = CH - CH = CH3
The major products obtained during ozonolysis of 2, 3-dimethyl-1-butene and subsequent reductions with Zn and H2O are
methanoic acid and 2-methyl-2-butanone
methanal and 3-methyl-2-butanone
methanol and 2, 2 -dimethyl-3-butanone
methanoic acid and 2-methyl-3-butanone
Choose the correct statement(s) among the following.
CH3CHO on reaction with HCN gives racemic mixture
CH3-CH=NOH shows geometrical isomerism
Which of the following statement(s) is (are) correct when a mixture of NaCl and K2Cr2O7 is gently warmed with conc. H2SO4?
A deep red vapour is evolved
The vapour when passed through NaOH solution, gives a yellow solution
Chlorine gas is also evolved
Chromyl chloride is formed