Amongst the following, which should have the highest rms speed at the same temperature?
SO2
CO2
O2
H2
In which of the following mixed aqueous solutions, pH =pKa at equilibrium?
(1) 100 mL of 0.1 M CH3COOH +100mL 0.1 M CH3COONa.
(2) 100 mL of 0.1 M CH3COOH + 50 mL of 0.1 M NaOH.
(3) 100 mL of 0.1 M CH3COOH + 100 mL of 0.1 M NaOH.
(4) 100 mL of 0.1 M CH3COOH + 100 mL of 0.1 M NH3.
(1) is correct
(2) is correct
(3) is correct
Both (1) and (2) are correct
Which statement is not correct for ortho and para hydrogen?
They have different boiling points
Ortho-form is more stable than para-form
They differ in their nuclear spin
The ratio of ortho to para hydrogen changes with change in temperature
Ozonolysis of an alkene produces only one dicarbonyl compound. The structure of the alkene is
H3C - CH = CH - CH3
CH3 - CH = CH - CH = CH3
The major products obtained during ozonolysis of 2, 3-dimethyl-1-butene and subsequent reductions with Zn and H2O are
methanoic acid and 2-methyl-2-butanone
methanal and 3-methyl-2-butanone
methanol and 2, 2 -dimethyl-3-butanone
methanoic acid and 2-methyl-3-butanone
Choose the correct statement(s) among the following.
CH3CHO on reaction with HCN gives racemic mixture
CH3-CH=NOH shows geometrical isomerism
Which of the following statement(s) is (are) correct when a mixture of NaCl and K2Cr2O7 is gently warmed with conc. H2SO4?
A deep red vapour is evolved
The vapour when passed through NaOH solution, gives a yellow solution
Chlorine gas is also evolved
Chromyl chloride is formed
A.
A deep red vapour is evolved
B.
The vapour when passed through NaOH solution, gives a yellow solution
D.
Chromyl chloride is formed
(A) When NaCl and K2Cr2O7 warmed with H2SO4 (i.e. in acidic medium), they produce deep red vapours of chromyl chloride (CrO2Cl2).
(B) When NaOH is passed, the product CrO3 formed in step (a) will react with NaOH and gives yellow colour solution.
(C) Chlorine gas is not evolved, thus false.
(D) In the given reaction, chromyl chloride (CrO2Cl2) is formed. All reactions are as follows: