The correct order of basicity of the following compounds is from

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

31.

The order of equivalent conductances at infinite dilution for LiCl, NaCl and KCl is

  • LiCl > NaCl > KCl

  • KCl > NaCl > LiCl

  • NaCl > KCl > LiCl

  • LiCl > KCl > NaCl


32.

Compound X is tested and the results are shown in the table.
Test Result
Aqueous sodium hydroxide is added, then heated gently. Gas given off which turns damp red litmus paper blue
Dilute hydrochloric acid is added. Effervescence, gas given off which turns lime water milky and acidified K2Cr2O7, paper green.

Which ions are present in compound X?

  • Ammonium ions and sulphite ions

  • Ammonium ions and carbonate ions

  • Sodium ions and carbonate ions

  • Ammonium ions and sulphate ions


33.

Amongst the following compounds, the one that wil not respond to Cannizzaro reaction upon treatment with alkali as

  • Cl3CCHO

  • Me3CCHO

  • C6H5CHO

  • HCHO


34.

Which of the following compounds would not react with Lucas reagent at room temperature?

  • H2C=CHCH2OH

  • C6H5CH2OH

  • CH3CH2CH2OH

  • (CH3)3COH


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35.

Amongst the following compounds, the one which would not respond to iodoform test is

  • CH3CH(OH)CH2CH3

  • ICH2COCH2CH3

  • CH3COOH

  • CH3CHO


36.

Which of the following will be dehydrated most readily in alkaline medium?


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37.

The correct order of basicity of the following compounds is

  • 1<2<3<4

  • 1<2<4<3

  • 2<1<3<4

  • 4<3<2<1


C.

2<1<3<4

The correct order is 2<1<3<4. Since, more the number of 2° -NH- group, more is the basic nature.
(i) Thus, 3 and 4 are more basic than 1 and 2.
(ii) Between 3 and 4, 4 has one two NH2 group while 3 has only one NH2 group.
     :. 4 is more basic than 3.
(iii) Between 1 and 2, 1 has one -NH2 group with no resonance, thus is more basic than 2.


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38.

Which of the following reaction will not result in the formation of carbon - carbon bonds?

  • Cannizzaro reaction

  • Wurtz reaction

  • Reimer-Tiemann reaction

  • Friedel-Crafts acylation


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39.

The correct structure of the drug paracetamol is


40.

Amongst the following compounds, the one(s) which readily react with ethanolic KCN.

  • Ethyl chloride

  • Chlorobenzene

  • Benzaldehyde

  • Salicylic acid


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