The correct basicity order of the following lanthanide ions is
La3+ > Lu3 > Ce3+ > Eu3+
Ce3+ > Lu3+ > La3+ > Eu3+
Lu3+ > Ce3+ > Eu3+ > La3+
La3+ > Ce3+ > Eu3+ > Lu3+
Assuming the compounds to be completely dissociated in aqueous solution, identify the pair of the solutions that can be expected to be isotonic at the same temperature.
0.01 M urea and 0.01 M NaCl
0.02 M NaCl and 0.01 M Na2SO4
0.03 M NaCl and 0.02 M MgCl2
0.01 M sucrose and 0.02 M glucose
In a close-packed body-centred cubic lattice of potassium, the correct relation between the atomic radius (r) of potassium and the edge-length (a) of the cube is
r =
r =
r =
r =
During electrolysis of molten NaCl, some water was added. What will happen?
Electrolysis will stop
Hydrogen will be evolved
Some amount of caustic soda will be formed
A fire is likely
The role of fluorspar, which is added in small quantities in the electrolytic reduction of alumina dissolved in fused cryolite is
as a catalyst
to make fused mixture conducting
to lower the melting temperature of the mixture
to decrease the rate of oxidation of carbon at anode
The compound that would produce a nauseating smell/ odour with a hot mixture of chloroform and ethanolic potassium hydroxide is
PhCONH2
PhNHCH3
PhNH2
PhOH
C.
PhNH2
When primary amine reacts with chloroform and ethanolic potassium hydroxide, they produce isocyamides as main product. The reaction is also known as carbylamine reaction.
Ph-NH2 Ph.N → C