The correct statement about ICl5 and ICl4- is: from Chemist

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

1.

For the following reactions, equilibrium constans are given:

S(s) + O2(g) SO2(g); K1 = 1052

2S(s) + 3O2(g) ⇌ 2SO3(g); K2 = 10129

The equilibrium constant for the reaction,

2SO2(s) + O2(g) ⇌ 2SO3(g)

  • 10181

  • 1077

  • 10154

  • 1025


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2.

The correct statement about ICl5 and ICl4- is:

  • ICl5 is trigonal bipyramidal and ICl4- is tetrahedral

  • ICl5 is square pyramidal and ICl4- is tetrahedral

  • both are isostructural

  • ICl5 is square pyramidal and ICl4- is square planar.


D.

ICl5 is square pyramidal and ICl4- is square planar.

ICl5 have 4 B.P and 1 L.P. It is square pyramidal. ICl4- have 4 B.P. and 2 L.P. The two L.P occupy opposite corners of octahedral. So it square planar.


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3.

Among the following molecules/ ions, 

C22-, N22-, O22-, O2

Which one is diamagnetic and has the shortest bond length?

  • O22-

  • C22-

  • N22-

  • O2


4.

The percentage composition of carbon by mole in methane is :

  • 20%

  • 25%

  • 75%

  • 80%


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5.

The strength of 11.2 volume solution of H2O2 is: [Given that molar mass of H=1 g mol–1 and O=16 g mol–1]

  • 1.7%

  • 34%

  • 13.6%

  • 3.4%


6.

If p is the momentum of the fastest electron ejected from a metal surface after the irradiation of light having wavelength λ, then for 1.5 p momentum of the photoelectron, the wavelength of the light should be: (Assume kinetic energy of ejected photoelectron to be very high in comparison to work function) :

  • 23λ

  • 49λ

  • 34λ

  • 12λ


7.

5 moles of an ideal gas at 100 K are allowed to undergo reversible compression till its temperature becomes 200 K. If CV = 28 J K–1 mol–1, calcuIate ΔU and ΔPV for this process. ( R= 8.0 JK-1 mol-1 )

  • ΔU = 14kJ; Δ(pV) = 18kJ

  • ΔU = 14kJ; Δ(pV) = 0.8J

  • ΔU = 14kJ; Δ(pV) = 4kJ

  • ΔU = 2.8kJ; Δ(pV) = o.8J


8.

The ion that has sp3d2 hybridization for the central atom, is:

  • [ICl4]-

  • [ICl2]-

  • [IF6]-

  • [BrF2]-


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9.

The maximum prescribed concentration of copper in drinking water is :

  • 0.5 ppm

  • 3 ppm

  • 0.05 ppm

  • 5 ppm


10.

The covalent alkaline earth metal halide (X = Cl, Br, I) is :

  • MgX2

  • BeX2

  • CaX2

  • SrX2


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