A process will be spontaneous at all temperatures if :
ΔH <0 and ΔS <0
ΔH <0 and ΔS >0
ΔH >0 and ΔS >0
ΔH >0 and ΔS <0
At 300k and 1 atmospheric pressure 10ml of a hydrocarbon required 55mL of O2 for complete combustion and 40mL of CO2 is formed. The formula of the hydrocarbon is:
C4H6
C4H7Cl
C4H8
C4H10
Consider the following table:
Gas | a/(kPa dm6mol-1) | b/(dm3mol-1) |
A | 642.32 | 0.05196 |
B | 155.21 | 0.04136 |
C | 431.91 | 0.05196 |
D | 155.21 | 0.4382 |
And b are vander walls contants . The correct statement a Bout the gases is :
Gas A will occupy than gas D Compressible than gas D Gas C will Occupy more volume than
gas A gas B will be more compressible than gas D Gas C will Occupy Lesser volume than
Gas A gas B will be more compressible than gas D Gas C will Occupy Lesser volume than
Gas A: gas B will be lesser Compressble than gas D
The graph between Ψ2 and r(radial diatance) is shown beow . This represents
2s orbital
2p orbital
3s orbital
1s orbital
Consider the following statements
a) The pH of a mixture containing 400mL of 0.1M H2SO4 and 400 mLof 0.1M NaOH will be approximately 1.3.
b) Ionic product of water is temperature dependent.
c) A monobasic acid with Ka=10-5 has a pH=5. The degree of dissociation of this acid is 50%.
d) The Le Chatelier’s Principle is not applicable to common-ion effect.
The correct statements are
b and c
a,b and d
a,b, and c
a and b
The isoelectronic set of ions is :
Li+, Na+, O2- and F-
N3-, O2-, F- and Na+
F-, Li+, Na+ and Mg2+
N3-,Li+, Mg2+ and O2-
The increasing order of the reactivity of the following compounds towards electrophilic aromatic substitution reactions is :
III < I <II
III< II<I
I< III< II
II< I < III