The correct order of acid strength is
HClO < HClO2 < HClO3 < HClO4
HClO4 < HClO < HClO2 < HClO3
HClO2 < HClO3 < HClO4 < HClO
HClO4 < HClO3 < HClO2 < HClO
The main reason for larger number of oxidation states exhibited by the actinides than the corresponding lanthanides, is
lesser energy difference between 5f and 6d orbitals than between 4f and 5d orbitals
larger atomic size of actinides than the lanthanide
more energy difference between 5f and 6d orbitals than between 4f and 5d orbitals
greater reactive nature of the actinides than the lanthanides
Aniline in a set of reactions yielded a product D
The structure of the product D would be
C6H5CH2NH2
C6H5NHCH2CH3
C6H5NHOH
C6H5CH2OH
In a set of reactions, acetic acid yielded a product D.
CH3COOH A B C D
The structure of D would be
Electrolytic reduction of nitrobenzene in weakly acidic medium gives
aniline
nitrosobenzene
N-phenylhydroxylamine
p-hydroxyaniline
Which of the following undergoes nucleophilic substitution exclusively by SN1 mechanism?
Benzyl chloride
Ethyl chloride
Chlorobenzene
lsopropyl chloride
A.
Benzyl chloride
Among all the given options, benzyl chloride undergoes SN1 mechanism.
Aliphatic SN1 reaction is carried out in two steps:
(i) carbonium (carbocation) ion is formed and its formation is based upon the stability.
Stability order of carbocation-
C6H52H2 > CH3 - H - CH3 > CH3 - H2
(ii) Nucleophile is attracted towards the carbonium ion in form of fast step to give final product.
Hence, in benzyl chloride, ethyl chloride and isopropyl chloride order of SN 1 reaction is benzyl chloride > isopropyl chloride > ethyl chloride
Which functional group participates in disulphide bond formation in proteins?
Thiolactone
Thiol
Thioether
Thioester