Dihedral angle between two methyl groups of n-butane in the gauche and anti forms are
60°, 0°
0°, 60°
60, 180°
180°, 60°
The vapour pressure of 100g water reduces from 3000 Nm-2 to 2985 Nm-2 when 5g of substance 'X' is dissolved in it. Substance 'X' is
methanol
glucose
carbon dioxide
cannot predict
The complex ion which has no d-electrons in the central metal atom is
[MnO4]-
[Co(NH3)6]3+
[Fe(CN)6]3-
[Cr(H2O)6]3+
White P reacts with caustic soda, the products are PH3 and NaH2PO2. This reaction is an example of
hydrolysis
reduction
disproportionation
neutralisation
C.
disproportionation
The above reaction is an example of disproportionation reaction, i.e. the reaction in which oxidation and reduction take place simultaneously.
The solubility of saturated solution of Ag2CrO4 is s mol L-1. What is its solubility product?
4s3
s3
2s3
16s2
For a reaction, A+ B Product, the rate is given by,
r = k[A]1/2[B]2
What is the order of the reaction?
0.5
2
2.5
1
How long it will take to deposit 1.0 g of chromium when a current of 1.25 A flows through a solution of chromium (III) sulphate ? (Molar mass of Cr = 52)
1.24 min
1.24 h
1.24 s
None of these
If a be the edge length of the unit cell and r be the radius of an atom then for fee arrangement, the correct relation is
4a = r
4r = a
4r = a
4r =
A solid AB has the NaCl structure. If radius of cation A+ is 120 pm, the maximum possible value of the radius of the anion B- is
240 pm
60 pm
49.6 pm
290 pm