IUPAC name of (CH3)3 CCl is
n-butyl chloride
3-chloro butane
2-chloro-2-methylpropane
t-butyl chloride
Hyperconjugation is most useful for stabilising which of the following carbocations?
Neo-pentyl
Tert-butyl
Iso-propyl
Ethyl
B.
Tert-butyl
On the basis of hyperconjugation, stability order of different alkyl carbocations is
3° > 2° > 1 ° > methyl
In t-butyl cation, the C-atom bearing the positive charge is attached to three methyl groups, thus it will have maximum hyperconjugate structures, which give it maximum stability.
The isomerism that arises due to restricted bond rotation is
metamerism
optical isomerism
position isomerism
geometrical isomerism
Which of the following undergoes reduction with hydrogen peroxide in alkaline medium?
Mn2+
I2
PbS
Fe2+
2 g of a radioactive sample having half-life of 15 days was synthesised on 1st Jan 2009. The amount of the sample left behind on 1st March, 2009 (including both the days) is
0 g
0.125 g
1 g
0.5 g
The rate equation for a reaction,
A B
is r = k[ A]0. If the initial concentration of the reactant is a mol dm-3 the half-life period of the reaction is