The correct increasing order of reactivity for the following molecules towards electrophilic aromatic substitution is
I < IV < II < III
I < IV < II < IV
I < III < II < IV
I < III < IV < II
The corrcet decreasing order of pKb is
I > II > III > IV
III > IV > II > I
II > III > IV > I
IV > II > I > III
The correct decreasing order of pKa is
II > IV > I > III
IV > II > III > I
III > II > IV > I
IV > I > II > III
Assertion: Dehydration of alcohols always takes place in basic medium.
Reason : OH- is a better leaving group.
If both assertion and reason are true and reason is the correct explanation of assertion
If both assertion and reason are true but reason is not the correct explanation of assertion
If assertion is true but reason is false
If both assertion and reason are false.
Assertion : Toluene in presence of UV rays forms benzaldehyde.
Reason : Dichlorotoluene is formed as an intermediate.
If both assertion and reason are true and reason is the correct explanation of assertion
If both assertion and reason are true but reason is not the correct explanation of assertion
If assertion is true but reason is false
If both assertion and reason are false.
Assertion : -pleated sheet structure of protein shows maximum extension.
Reason : Intermolecular hydrogen bonding is present in them.
If both assertion and reason are true and reason is the correct explanation of assertion
If both assertion and reason are true but reason is not the correct explanation of assertion
If assertion is true but reason is false
If both assertion and reason are false
Assertion : Fructose is a reducing sugar.
Reason : It has a ketonic group.
If both assertion and reason are true and reason is the correct explanation of assertion
If both assertion and reason are true but reason is not the correct explanation of assertion
If assertion is true but reason is false
If both assertion and reason are false.
Assertion : p-Nitrophenol gives more electrophilic substituted compound than m-methoxyphenol.
Reason : Methoxy group shows only negative I-effect.
If both assertion and reason are true and reason is the correct explanation of assertion
If both assertion and reason are true but reason is not the correct explanation of assertion
If assertion is true but reason is false
If both assertion and reason are false.
D.
If both assertion and reason are false.
In p-nitrophenol, - NO2 group has -I effect, as a result of which electron density decreases on the benzene ring, hence reactivity towards electrophilic substitution decreases. Methoxy group shows both +R (due to lone pair of electrons on O) and -I effect (due to greater electronegativity of O).
OCH3 at meta-position shows only -I effect but lesser than -I effect of -NO2 group.