Solubility of the alkaline earth s metal sulphates in water decr

Subject

Chemistry

Class

NEET Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

1.

Which of the following species contains an equal number of σ and Π bond? 

  • HCO3-

  • XeO4

  • (CN)2

  • (CN)2

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2.

The species Ar, K+ and Ca2+ contain the same number of electrons. In which order do their radii increase?

  • Ar < K+< Ca2+

  • Ca2+ < Ar < K+

  • Ca2+ < K+ < Ar

  • Ca2+ < K+ < Ar

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3.

Solubility of the alkaline earth's metal sulphates in water decreases in the sequence

  • Mg>Ca>Sr>Ba

  • Ca>Sr>Ba>Mg>

  • Sr>Ca>Mg>Ba

  • Sr>Ca>Mg>Ba


A.

Mg>Ca>Sr>Ba

The solubility of the sulphates. The sulphates becomes less soluble as  you fo down the group i.e

Mg> Ca>Sr> Ba

The magnitude of the lattice energy remains almost constant as the size of the sulphate ion is so big that small increase in the size of the cation from Be to Ba does not make any difference. However, the hydration energy decreases from Be2+ to Ba2+ appreciably as the size of the cation increases down the group. The significantly high solubility of MgSO4 is due to high enthalpy of solvation on the smaller Mg2+ ions.

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4.

Which of the following pairs of ions are isoelectronic and isostructural? 

  • CO subscript 3 superscript 2 minus end superscript comma space SO subscript 3 superscript 2 minus end superscript
  • ClO subscript 3 superscript minus comma space CO subscript 3 superscript 2 minus end superscript
  • SO subscript 3 superscript 2 minus end superscript comma NO subscript 3 superscript minus
  • SO subscript 3 superscript 2 minus end superscript comma NO subscript 3 superscript minus
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5.

Magnetic moment 2.84 BM is given by (At. no. Ni= 28, Ti= 22, Cr=24, Co = 27)

  • Ni2+

  • Ti3+

  • Cr3+

  • Cr3+

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6.

If the value of an equilibrium constant ofr particular reaction is 1.6 x1012 then at equilibrium the system will contains

  • all reactants

  • mostly reactants

  • mostly products

  • mostly products

1313 Views

7.

The number of d- electrons in Fe2+ (Z = 26) is not equal to the number of electrons in which one of the following?

  • S- electronic in Mg (Z=12)

  • p-electrons in Cl( Z=17)

  • d- electrons in Fe (Z=26)

  • d- electrons in Fe (Z=26)

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8.

The angular momentum of electrons in d orbital is equal to

  • square root of 6 space h
  • square root of 2 straight h
  • 2 square root of 3 straight h
  • 2 square root of 3 straight h
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9.

The Ksp of Ag2CrO4, AgCl, AgBr and AgI are respectively, 1.1 x 10-12, 1.8 x 10-11, 8.3 x 10-17. Which one of the following salts will precipitate last if AgNO3 solution is added to the solution containing equal moles of NaCl, NaBr, NaI and Na2CrO4

  • AgI

  • AgCl

  • AgBr

  • AgBr

4272 Views

10.

Which of the following statements is correct for a reversible process in a state of equilibrium?

  • ΔG = -2.303RT log K
  • ΔG = 2.303RT log K

  • ΔG0 = -2.303RT log K

  • ΔG0 = -2.303RT log K

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