Which of the following species contains an equal number of σ and Π bond?
HCO3-
XeO4
(CN)2
(CN)2
The species Ar, K+ and Ca2+ contain the same number of electrons. In which order do their radii increase?
Ar < K+< Ca2+
Ca2+ < Ar < K+
Ca2+ < K+ < Ar
Ca2+ < K+ < Ar
Solubility of the alkaline earth's metal sulphates in water decreases in the sequence
Mg>Ca>Sr>Ba
Ca>Sr>Ba>Mg>
Sr>Ca>Mg>Ba
Sr>Ca>Mg>Ba
Magnetic moment 2.84 BM is given by (At. no. Ni= 28, Ti= 22, Cr=24, Co = 27)
Ni2+
Ti3+
Cr3+
Cr3+
If the value of an equilibrium constant ofr particular reaction is 1.6 x1012 then at equilibrium the system will contains
all reactants
mostly reactants
mostly products
mostly products
The number of d- electrons in Fe2+ (Z = 26) is not equal to the number of electrons in which one of the following?
S- electronic in Mg (Z=12)
p-electrons in Cl( Z=17)
d- electrons in Fe (Z=26)
d- electrons in Fe (Z=26)
B.
p-electrons in Cl( Z=17)
Electronic configuration of Fe2+ is [Ar]3d6 4s0
therefore, Number of electrons = 6
Mg- 1s2 2s2 2p6 (6s electrons)
It matches with the 6d electrons of Fe2+
Cl- 1s2 2s2 2p6 3s2 3p5 (11 p electrons)
It does not match with the 6d electrons of Fe2+
Fe- [Ar] 3d6 4s2 (6d electrons)
It does not match with the 6d electrons of Fe2+
Ne- 1s2 2s2 2p6 3s2 3p 6 (6p electrons)
It matches with the 6d electrons of Fe2+.
Hence, Cl has 11 p electrons which do not match in number with 6d electrons of Fe2+
The Ksp of Ag2CrO4, AgCl, AgBr and AgI are respectively, 1.1 x 10-12, 1.8 x 10-11, 8.3 x 10-17. Which one of the following salts will precipitate last if AgNO3 solution is added to the solution containing equal moles of NaCl, NaBr, NaI and Na2CrO4?
AgI
AgCl
AgBr
AgBr
Which of the following statements is correct for a reversible process in a state of equilibrium?
ΔG = 2.303RT log K
ΔG0 = -2.303RT log K
ΔG0 = -2.303RT log K