Consider the following compounds
Hyperconjugation occurs in
I only
II only
III only
III only
The enolic form of ethyl acetoacetate as below has
18 sigma bonds and 2 pi-bond
16 sigma bonds and 1 pi-bond
9 sigma bonds and 2 pi-bond
9 sigma bonds and 2 pi-bond
'Metals are usually not found as nitrates in their ores'
Out of the following two (a and b) reasons which isare/are true for the above observation?
I. Metal nitrates are highly unstable.
II.Metal nitrates are highly soluble in water.
I and II are true
I and II are false
I is false but II is true
I is false but II is true
C.
I is false but II is true
Metals are usually not found as nitrates in their ores, because metal nitrates are highly soluble in water. For example, KNO3 (salt peter) would be classified as completely soluble. Thus, KNO3 could be expected to dissociate completely in aqueous solution into K+ and NO3- ions.
The nitrate anion has three equivalent oxygen surrounding a central nitrogen atom. This tends to spread the single negative charge and make it easier for water to separate the ions in solution.
Because of lanthanoid contraction, of elements which of the following elements have nearly same atomic radii ? (Number in the parenthesis are atomic number).
Ti (22) and Zr(40)
Zr(40) and Nb (41)
Zr (40) and Hf (72)
Zr (40) and Hf (72)
Which of the following processes does not involve oxidation of iron?
Rusting of iron sheets
Decolourisation of blue CuSO4 solution by iron
Formation of Fe(CO)5 from Fe
Formation of Fe(CO)5 from Fe
Which of the following options represents the correct order?
O2-> O2>O2+
O2-<O2<O2+
O2->O2<O2+
O2->O2<O2+
Nitogen dioxide and sulphur dioxide have some properties in common. which property is shown by one of these, comounds but not the order?
Forms acid -rain
Is a reducing -agent
Is a soluble in water
Is a soluble in water
The maximum bond angle at nitrogen is present in which of the following?
NO2
NO2-
NO2+
NO2+
Which of these statements about [Co(CN)6]3- is true?
[Co(CN)6]3- has no unpaired electrons and will be in a low-spin configuration.
[Co(CN)6]3- has four unpaired electrons and will be in a low-spin configuration
[Co(CN)6]3- has four unpaired electrons and will be in high-spin configuration.
[Co(CN)6]3- has four unpaired electrons and will be in high-spin configuration.