The manganate and permanganate ions are tetrahedral, due to : fr

Subject

Chemistry

Class

NEET Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

1.

A gas at 350 K and 15 bar has molar volume 20 percent smaller than that for an ideal gas under the same conditions. The correct option about the gas and its compressibility factor (Z) is :

  • Z > 1 and repulsive forces are dominant

  • Z < 1 and attractive forces are dominant

  • Z < 1 and repulsive forces are dominant

  • Z > 1 and attractive forces are dominant


2.

4d, 5p, 5f and 6p orbitals are arranged in the order of decreasing energy. The correct option is:

  • 6p > 5f > 5p > 4d

  • 6p > 5f > 4d > 5p

  • 5f > 6p > 4d > 5p

  • 5f > 6p > 5p > 4d


3.

Which will make basic buffer?

  • 100mL of 0.1 M CH3COOH + 100mL of 0.1M NaOh

  • 100 mL of 0.1 M HCl + 200 mL of 0.1 M NH4OH

  • 100 mL of 0.1 M HCl + 100 mL of 0.1 M NaOH

  • 50 mL of 0.1 M NaOH + 25 mL of 0.1 M CH3COOH


4.

Which of the following diatomic molecular species has only π bonds according to Molecular Orbital Theory?

  • N2

  • C2

  • Be2

  • O2


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5.

Under isothermal condition, a gas at 300 K expands from 0.1 L to 0.25 L against a constant external pressure of 2 bar. The work done by the gas is:(Given that 1 L bar = 100 J)

  • 5 kJ

  • 25 J

  • 30 J

  • -30 J


6.

Which of the following series of transitions in the spectrum of hydrogen atom fall in visible region?

  • Balmer series

  • Paschen series

  • Brackett series

  • Lyman series


7.

Conjugate base for BrÖnsted acids H2O and HF are :

  • H3O+ and F-, respectively

  • OH- and F-, respectively

  • H3O+ and  H2F+, respectively

  • OH- and H2F+, respectively


8.

In which case change in entropy is negative?

  • Expansion of a gas at constant temperature

  • Sublimation of solid to gas

  • 2H(g) → H2(g)

  • Evaporation of water


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9.

The manganate and permanganate ions are tetrahedral, due to :

  • There is no π-bonding

  • The π- bonding involves overlap of p-orbitals of oxygen with p-orbitals of manganese.

  • The π-bonding involves overlap of d-orbitals of oxygen with d-orbitals of manganese

  • The π-bonding involves overlap of p-orbitals of oxygen with d-orbitals of manganese


D.

The π-bonding involves overlap of p-orbitals of oxygen with d-orbitals of manganese

(i) Manganate (MnO42-): 

π- bonds are of dπ-pπ type.

(ii) Permanganate (MnO4-): 

π- bonds are of dπ-pπ type.


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10.

pH of a saturated solution of Ca(OH)2 is 9. The solubility product(Ksp) of Ca(OH)2 is:

  • 0.25 × 10-10

  • 0.5 × 10-15

  • 0.125 × 10-15

  • 0.5 × 10-10


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