These conversions are based on the fact that:
(a) Chlorine is ortho and para directing in nature.
(b) Nitro group is meta directing in nature.
(i) Benzene into p-nitro bromobenzene
(ii) Benzene into m-nitro chlorobenzene.
(iii) Benzene into p-nitrotoluene.
(iv) Benzene into acetophenone.