In the extraction of copper from its sulphide ore, the metal is finally obtained by the reduction of cuprous oxide with

  • Copper (I) sulphide (Cu2S)

  • sulphur dioxide (SO2)

  • Iron sulphide (FeS)

  • Iron sulphide (FeS)


A.

Copper (I) sulphide (Cu2S)

In the extraction of copper from its sulphide ore, when ore is subjected to roasting, some of it is oxidised to Cu2O which reacts with the remaining Cu2S (sulphide ore) to give copper metal.
Cu2S +2Cu2O → 6Cu +SO2 ↑
In this process, Cu2S behaves as reducing agent. 

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Which of the following pairs of metals is purified by van Arkel method?

  • Zr and Ti

  • Ag and Au

  • Ni and Fe

  • Ni and Fe


A.

Zr and Ti

Zr and Ti are purified by van Arkel method.

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Which of the following elements is present as the impurity to the maximum extent in the big iron?

  • Carbon

  • Silicon

  • Phosphorus

  • Phosphorus


A.

Carbon

Pig iron contains about 4% carbon (major impurity) and other impurities (S, P, Si, Mn) in trace amount.

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Identify the alloy containing a non-metal as a constituent in it.

  • Invar

  • Steel

  • Bell metal

  • Bell metal


B.

Steel

Alloy

Constituents

Invar

Fe + Ni

Steel

Fe + C

Bell metal

Cu (80%) +Sn (20%)

Bronze

Cu (75,90%) +Sn (10.25%)


Among these alloys only steel cotains carbon, which is a non-metal.
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In the extraction of copper from its sulphide ore, the metal finally obtained by the reduction of cuprous oxide with 

  • Iron (II) sulphide

  • Carbon monoxide

  • Copper (I) sulphide

  • Copper (I) sulphide


C.

Copper (I) sulphide

Reduction of Copper oxide done with Copper (I) sulphide.

Cu2S + 2Cu2O → 6Cu +SO2 ↑

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