Write formulas for the following compounds:(a) Mercury (II) chlo
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Write formulas for the following compounds:
(a) Mercury (II) chloride
(b) Nickel (II) sulphate
(c) Tin (IV) oxide
(d) Thallium (I) sulphate
(e) Iron (III) sulphate
(f) Chromium (III) oxide


Formula of Given Compounds are:
(a) HgCl
2 
(b) NiSO
4 
(c) SnO
2
(d) TI2SO4
(e) Fe2(SO4)3
(f) Cr2O3.
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Fluorine reacts with ice and results in the change:
H2O(s) + F2(g) → HF(g) + HOF (g)
Justify that this reaction is a redox reaction.


In a redox reaction, one of the reacting species is to undergo an increase in Oxidation Number and other must undergo a decrease in Oxidation Number based upon this, the given reaction is redox reaction.



Here F
2 is oxidised to HOF and reduced to HF, therefore it is a redox reaction.
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Consider the reactions:
bold left parenthesis bold a bold right parenthesis bold space bold space bold 6 bold CO subscript bold 2 bold left parenthesis bold g bold right parenthesis bold space bold plus bold space bold 6 bold H subscript bold 2 bold O bold left parenthesis bold l bold right parenthesis bold space bold space bold rightwards arrow bold space bold space bold space bold C subscript bold 6 bold H subscript bold 12 bold O subscript bold 6 bold left parenthesis bold aq bold right parenthesis bold space bold plus bold space bold 6 bold O subscript bold 2 bold left parenthesis bold g bold right parenthesis
Why is it more appropriate to write these reactions as:
bold left parenthesis bold a bold right parenthesis bold space bold 6 bold CO subscript bold 2 bold left parenthesis bold g bold right parenthesis bold space bold plus bold space bold 12 bold H subscript bold 2 bold O bold left parenthesis bold l bold right parenthesis bold space bold space
bold space bold space bold space bold space bold space bold space bold space bold space bold space bold space bold rightwards arrow bold space bold space bold space bold C subscript bold 6 bold H subscript bold 12 bold O subscript bold 6 bold left parenthesis bold aq bold right parenthesis bold space bold plus bold space bold 6 bold H subscript bold 2 bold O bold left parenthesis bold I bold right parenthesis bold space bold plus bold space bold 6 bold O subscript bold 2 bold left parenthesis bold g bold right parenthesis
bold left parenthesis bold b bold right parenthesis bold space bold O subscript bold 3 bold left parenthesis bold g bold right parenthesis bold space bold plus bold space bold H subscript bold 2 bold O subscript bold 2 bold left parenthesis bold l bold right parenthesis bold space bold space bold rightwards arrow bold space bold space bold space bold space bold space bold H subscript bold 2 bold O bold left parenthesis bold l bold right parenthesis bold space bold plus bold space bold O subscript bold 2 bold left parenthesis bold g bold right parenthesis bold space bold plus bold space bold O subscript bold 2 bold left parenthesis bold g bold right parenthesis

Also, suggest a technique to investigate the path of the above (a) and (b) redox reactions. 


(a) Although the mechanism of photosynthesis is very complex but broadly speaking it may be visualised to occur in two steps. In the first step, H2O decomposes to give H2 and O2 in the presence of chlorophyll and H2 thus produced reduces CO2 to C6H12O6 in the second step. During the second step, some H2O molecules are also produced as


Therefore, it is more appropriate, to write the equation for photosynthesis as (3) because it emphasises that 12H2O are used per molecule of carbohydrate formed and 6H2O are produced during the process.

(b) The purpose of writing O2 two times suggests that O2 is being obtained from each of the two reactants.
                  
The path of reactions (a) and (b) can determine by using  in reaction (a) or by using 
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While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agent is their reactions, ozone and nitric acid act only an oxidants. Why? 

In sulphur dioxide (SO2) and hydrogen peroxide (H2O2), the oxidation states of sulphur and oxygen are +4 and -1 respectively. As these can increase as well as decrease when the compounds take part in chemical reactions, hence they can act as oxidising as well as reducing agents. Example,

In hydrogen peroxide H2O2, the oxidation number of O is -1 and the range of the Oxidation number that O can have are from O to -2 can sometimes also attain the oxidation numbers +1 and +2. Hence, H2O2 can act  as an oxidising as well as reducing agent.


In ozone (O
3), the oxidation state of oxygen is zero while in nitric acid (HNO3), the oxidation state of nitrogen is +5. As both can undergo decrease in oxidation state and not an increase in its value, hence they can act only as oxidants and no as reductants.

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Assign oxidation number of the underlined elements in each of the following species:
space space space NaH subscript 2 bottom enclose straight P straight O subscript 4



Let the oxidation number of P = x
Writing the oxidation number of each atom at the top of its symbol.
                 +1 + 1 x - 2
                 Na  H2PO4    
Sum of the oxidation number of various atoms = 0
                                +1+2(+1)+x+4(-2) = 0
                                        x - 5 = 0
or                                      x = 5
  Oxidation number of P in NaH2PO4 = 5 
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