At STP, a container has 1 mole of Ar, 2 moles of CO2, 3 moles of

Subject

Chemistry

Class

JEE Class 12

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11.

At STP, a container has 1 mole of Ar, 2 moles of CO2, 3 moles of O2, and 4 moles of N2. Without changing the total pressure if one mole of O2 is removed, the partial pressure of O2 is

  • changed by about 16%

  • halved

  • changed by 26%

  • unchanged


C.

changed by 26%

 Mole fraction of A =moles of Atotal molesGiven, Moles of Ar = 1, moles of CO2= 2,moles of O2 =3, moles of N2= 4,moles of O2  at initial stage=31+2+3 +4×100 =310×100= 30Mole fraction of O2 at final stage =310-21+2+2 +4=310-29× 100=7098 % change =830× 100= 26%


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12.

In a compound C, H and N are present in 9 : 1 : 3.5 by weight. If molecular weight of the compound is 108, then the molecular formula of the compound is

  • C2H6N2

  • C3H4N

  • C6H8N2

  • C9H12N3


13.

What amount of bromine will be required to convert 2 g of phenol into 2, 4, 6-tribromo phenol?

  • 4.00

  • 6.00

  • 10.22

  • 20.44


14.

The energy of hydrogen atom in its ground state is -13.6 eV. The energy of the level corresponding to the quantum number n = 5 is

  • -5.4 eV

  • -0.54 eV

  • -2.72 eV

  • -0.85 eV


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15.

What is the amount of urea dissolved per litre, if aqueous solution is isotonic with 10% cane sugar solution (mol. wt. of urea = 60) ?

  • 200 g/L

  • 19.2 g/L

  • 17.54 g/L

  • 16.7 g/L


16.

Conjugate acid S2O82-

  • H2S2O8

  • H2SO4

  • HS2O8-

  • HSO4-


17.

The equilibrium constant of a reaction is 300. If the volume of reaction flask is tripled, the equilibrium constant is

  • 300

  • 600

  • 900

  • 100


18.

The COgas does not follow gaseous laws at all ranges of pressure and temperature because

  • it is triatomic gas

  • its internal energy is quite high

  • there is attraction between its molecules

  • it solidify at low temperature


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19.

A 0.01 M ammonia solution is 5% ionised, its pH will be

  • 11.80

  • 10.69

  • 7.22

  • 12.24


20.

In clatherates of xenon with water, the nature of bonding between xenon and water molecule is

  • dipole induced dipole interaction

  • coordinate

  • hydrogen bonding

  • covalent


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