Which of the following substance is not related with HVZ reaction

Subject

Chemistry

Class

JEE Class 12

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 Multiple Choice QuestionsMultiple Choice Questions

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21.

Which of the following substance is not related with HVZ reaction?

  • α-bromo acetic acid

  • Zn/ Hg

  • Cl2

  • Red P


B.

Zn/ Hg

α- hydrogen of a carboxylic acid can be replaced by halogen (chlorine or bromine) using red phosphorus as catalyst to afford an a-halocarboxylic acid. This reaction is called Hell-Volhard-Zelinsky reaction.

R-CH2-COOHX2carboxylic acid Red P R-C(X)H-COOH + HXα-halocarboxylic acid


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22.

The electronic configuration of an element C is 1s2, 2s2, 2p6. The formula of substance containing only C will be

  • C8

  • C4

  • C2

  • C


23.

Which of the following compound show acidic nature?

  • but-1-yne

  • but-2-yne

  • but-1-ene

  • buta-1, 3-diene


24.

Kjeldahl trap is

  • fitted over Kjeldahl flask

  • used to trap water vapours

  • used to trap ammonia

  • None of the above


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25.

The hydration energy of Mg2+ ions is higher than that of

  • Al3+

  • Be2+

  • Na+

  • None of these


26.

See the following redox reaction

A2+ + 2e- → A; E° = +0.34 V

   A+ + e- → A; E° = +0.52 V

Which ion is expected to be stable?

  • A2+

  • A+

  • Both can form stable complexes

  • None can form stable complexes


27.

The first ionisation potential (in eV) of N and O atoms are

  • 14.6, 13.6

  • 13.6, 14.6

  • 13.6, 13.6

  • 14.6, 14.6


28.

The dimensions of a unit cell of a crystal are a = 0.397, b = 0.387, c = 0.504 and α = β = 90°, γ = 120° the crystal system is

  • cubic

  • hexagonal

  • orthorhombic

  • rhombohedral


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29.

Which one of the following has minimum gold number?

  • Starch

  • Sodium oleate

  • Gelatin

  • Gum arabic


30.

Which gas behaves abnormally when liquified?

  • Xenon

  • Krypton

  • Helium

  • Argon


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