Which one of the following alkenes when treated with HCl yields m

Subject

Chemistry

Class

JEE Class 12

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11.

Which one of the following alkenes when treated with HCl yields majority an anti Maxkovnikov product?

  • CH3O-CH=CH2

  • Cl-CH=CH2

  • F3C-CH=CH2

  • H2N-CH=CH2


C.

F3C-CH=CH2

H3CO-CH=CH2 HCl H3CO-CHCl-CH3 Markonikov's productF3C-CH=CH2 HCl F3C-CH2-CH2Cl Anti Markonikov's productCl-CH=CH2 HClCl-CHCl-CH3 Markonikov's productH2N-CH=CH2 HClH2N-CHCl-CH3 Markonikov's product


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12.

Polysubstitution is a major drawback in

  • Friedel Craf t’ s alkylation

  • Reimer Tiemann reaction

  • FriedelCraft's acylation

  • Acetylation of aniline


13.

0.27 g of a long chain fatty acid was dissolved in 100 cm3 of hexane. 10 mL of this solution was added dropwise to the surface of water in a round watch glass. Hexane evaporates and a monolayer is formed. The distance from edge to centre of the watch glass is 10 cm. What is the height of the monolayer ?[Density of fatty acid = 0.9 g cm-3, π=3]

  • 10-6 m

  • 10-2 m

  • 10-4 m

  • 10-8 m


14.

The compound that inhibits the growth of tumors is:

  • trans-[Pt(Cl)2(NH3)2]

  • trans-[Pd(Cl)2(NH3)2]

  • cis-[Pd(Cl)2(NH3)2]

  • cis-[Pt(Cl)2(NH3)2]


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15.

For a reaction scheme A k1 B k2C, if the rate of formation of B is set to be zero then the concentration of B is given by:

  • (k1 + k2)[A]

  • (k1 - k2)[A]

  • k1k2[A]

  • k1k2[A]


16.

Calculate the standard cell potential (in V) of the cell in which following reaction takes place :

Fe2+ (aq) + Ag+(aq) → Fe3+(aq) + Ag(s)

Given that 

Ag+/ Ag = xV

Fe2+/ Fe = yV

Fe3+/ Fe = zV

  • x -y

  • x-z

  • x +2y-3z

  • x+y-z


17.

The calculated spin–only magnetic moments (BM) of the anionic and cationic species of [Fe(H2O)6]2 and [Fe(CN)6], respectively, are :

  • 4.9 and 0

  • 2.84 and 5.92

  • 0 and 5.92

  • 0 and 4.9


18.

The IUPAC symbol for the element with atomic number 119 would be:

  • uun

  • uue

  • uuh

  • une


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19.

The Mond process is used for the:

  • extraction of Zn

  • purification of Ni

  • purification of Zr and Ti

  • extraction of Mo


20.

The statement that is INCORRECT about the interstitial compounds is :

  • they are chemically reactive

  • they have metallic conductivity

  • they have high melting points

  • they are very hard


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